{"id":"W2121953512","doi":"10.1021/jp0007235","title":"Tunneling Time for Electron Transfer Reactions","year":2000,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":98,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"Office of Naval Research; Multidisciplinary University Research Initiative; U.S. Department of Defense; National Science Foundation","keywords":"Superexchange; Quantum tunnelling; Electron transfer; Electron; Coupling (piping); Limit (mathematics); Physics; Condensed matter physics; Chemistry; Atomic physics; Quantum mechanics; Materials science; Ferromagnetism","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001200192,0.0003396575,0.0003710604,0.0009174205,0.0004143088,0.0006373749,0.0007264779,0.0007097898,0.007271667],"category_scores_gemma":[0.00497941,0.0001582635,0.0004478935,0.0005394236,0.0004043822,0.002744475,0.0003613245,0.001026098,0.0005989139],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001110806,"about_ca_system_score_gemma":0.0005853806,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004399201,"about_ca_topic_score_gemma":0.0002166665,"domain_scores_codex":[0.9996412,0.00003758014,0.00001648921,0.0001217703,0.0001266827,0.00005639979],"domain_scores_gemma":[0.9981535,0.001268074,0.0001276575,0.000172696,0.000189971,0.00008798631],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.000956669,0.0001810795,0.004452229,0.0008510636,0.00008478507,0.0004148861,0.0004639655,0.1214824,0.1181313,0.6792322,0.001450247,0.07229909],"study_design_scores_gemma":[0.00007464842,0.0003386612,0.003612097,0.0001048955,0.0001360042,0.0009963774,0.0001410979,0.7643158,0.1002333,0.1211149,0.008810846,0.0001213749],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":"theoretical_or_conceptual","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5884566,0.00424617,0.3842365,0.0006239603,0.0003366946,0.0001222499,0.0007287645,0.001080552,0.02016846],"genre_scores_gemma":[0.970306,0.001415039,0.02131804,0.00005698387,0.00002937077,0.00006473526,0.0005577782,0.0001373759,0.006114652],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007271667,"threshold_uncertainty_score":0.02432621,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003215382934410982,"score_gpt":0.1956095673150147,"score_spread":0.1923941843806037,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}