{"id":"W2122061636","doi":"10.1002/9780470682531.pat0158","title":"Rearrangements of Hydrazo, Azoxy and Azo Compounds: Kinetic, Product and Isotope Studies","year":2009,"lang":"en","type":"other","venue":"","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University; University of Toronto","funders":"","keywords":"Azoxy; Chemistry; Isotope; Kinetic energy; Product (mathematics); Radiochemistry; Kinetic isotope effect; Organic chemistry; Mathematics; Physics; Nuclear physics; Deuterium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005698032,0.0002753632,0.0004895663,0.00006903676,0.00001882731,0.00001610165,0.0001040766,0.0001631594,0.002098487],"category_scores_gemma":[0.00009185848,0.0002342593,0.00003720247,0.00005306754,0.0001195389,0.00002160625,0.0001144971,0.0001581399,0.00001268449],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002667357,"about_ca_system_score_gemma":0.00001044807,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001028246,"about_ca_topic_score_gemma":0.00003627689,"domain_scores_codex":[0.9989045,0.000007061351,0.0002407379,0.0004471068,0.0002319414,0.0001686333],"domain_scores_gemma":[0.9992913,0.00004075043,0.0001928758,0.0003530608,0.00004902402,0.00007297665],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00002107774,0.00009277824,0.00008272655,0.001087155,0.0003057874,0.000004895348,0.00007805527,3.01711e-8,0.6204349,0.0001748958,0.3702173,0.007500355],"study_design_scores_gemma":[0.0006992143,0.00003179747,0.00002631736,0.0005604779,0.0001243497,0.0000145789,0.0001530199,0.000003660316,0.3412349,0.0006434644,0.6561657,0.0003425561],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.005868438,0.00767002,0.000006314851,0.0001796045,0.00008723565,0.0002053627,0.00002750369,0.0001633567,0.9857922],"genre_scores_gemma":[0.01472451,0.005890926,0.00194038,0.000108424,0.0002795983,0.00001674849,0.00003214396,0.0002024141,0.9768049],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.2859483,"threshold_uncertainty_score":0.9988137,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02199551744042219,"score_gpt":0.2768422064541369,"score_spread":0.2548466890137147,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}