{"id":"W2122645227","doi":"10.1039/b514952e","title":"Making use of crystallization-induced asymmetric transformations in solid state organic photochemistry: application to the enantioselective Yang photocyclization of endo-bicyclo[2.1.1]hexyl aryl ketones","year":2005,"lang":"en","type":"article","venue":"CrystEngComm","topic":"Molecular spectroscopy and chirality","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Curtin University of Technology","keywords":"Diastereomer; Chemistry; Crystallization; Diazomethane; Aryl; Bicyclic molecule; Enantioselective synthesis; Enantiomer; Amine gas treating; Salt (chemistry); Solid-state; Medicinal chemistry; Photochemistry; Stereochemistry; Organic chemistry; Alkyl; Physical chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002392397,0.0002245761,0.0003335406,0.0001960227,0.0001251979,0.00004383735,0.0003502702,0.0001281784,0.00009907355],"category_scores_gemma":[0.0002136057,0.0002044312,0.0001102143,0.001294239,0.00004128816,0.0002618651,0.00005140611,0.0002270367,0.000004335158],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001912767,"about_ca_system_score_gemma":0.00009465541,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001219114,"about_ca_topic_score_gemma":0.0004318632,"domain_scores_codex":[0.9982127,0.00005347528,0.0007977309,0.0003049312,0.0003404698,0.00029071],"domain_scores_gemma":[0.9986063,0.0001339836,0.0003982078,0.0005694006,0.0002303779,0.00006168125],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000611779,0.0002096699,0.002102198,0.0002154806,0.0000463085,5.534653e-7,0.002194692,0.002654754,0.9899015,0.0002539356,0.00002735681,0.002332386],"study_design_scores_gemma":[0.0005189387,0.0000255145,0.002245321,0.0001370535,0.00004174584,0.00000566814,0.0002521579,0.007082003,0.9882885,0.0001450244,0.001057284,0.0002008081],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9103794,0.0000857792,0.08676852,0.0002151381,0.00002160048,0.0007156795,0.00007943669,0.00005488793,0.001679523],"genre_scores_gemma":[0.99876,0.00004079842,0.0006595209,0.00009058556,0.00004664049,0.0002031117,0.000109278,0.00003495563,0.00005504306],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08838063,"threshold_uncertainty_score":0.8336462,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02130866883219903,"score_gpt":0.2881728424876973,"score_spread":0.2668641736554983,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}