{"id":"W2123064630","doi":"10.1139/v00-091","title":"Preparation and characterization of organic-inorganic hybrid materials incorporating diphosphino moieties. Study of the accessibility of the phosphorus atoms included into the material","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Polyoxometalates: Synthesis and Applications","field":"Materials Science","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Diphosphines; Reagent; Hydrolysis; Phosphorus; Hybrid material; Molecule; Condensation polymer; Inorganic chemistry; Polymer chemistry; Crystallography; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001064911,0.0001731171,0.00008418778,0.0001946258,0.0001260462,0.0001962912,0.0001238307,0.0001818601,0.0008106689],"category_scores_gemma":[0.0001653134,0.0001062832,0.00007694832,0.0001138982,0.0001557045,0.0001961436,0.0001335889,0.0001608805,0.0002051107],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000120669,"about_ca_system_score_gemma":0.0000984467,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002371756,"about_ca_topic_score_gemma":0.0007466566,"domain_scores_codex":[0.9999444,0.000003941279,0.000003946695,0.0000153072,0.00002151177,0.00001094852],"domain_scores_gemma":[0.9999223,0.00002164908,0.00001776781,0.00001048177,0.00001444765,0.00001336199],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001191218,0.000005118106,0.00005407894,0.00002085892,0.000001330531,0.00001952183,0.000007600878,0.00003234425,0.9991269,0.00003186003,0.000007298123,0.0006812539],"study_design_scores_gemma":[0.000004159284,0.00005641481,0.0008477879,0.000001361855,0.000005731787,0.00007041146,0.000008614163,0.0001558838,0.9978393,0.00001560085,0.0009928856,0.000001846553],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9891703,0.0006244596,0.007584256,0.00004381001,0.00001434232,0.00005605267,0.0004034138,0.00007497365,0.002028462],"genre_scores_gemma":[0.9814594,0.0004269767,0.01458498,0.00002838575,0.000007182355,0.00005909962,0.0006986784,0.00003893134,0.002696304],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008106689,"threshold_uncertainty_score":0.002712011,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006825408790117172,"score_gpt":0.2200152640041593,"score_spread":0.2131898552140421,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}