{"id":"W2123166275","doi":"10.1038/nchem.1270","title":"Strongly coupled binuclear uranium–oxo complexes from uranyl oxo rearrangement and reductive silylation","year":2012,"lang":"en","type":"article","venue":"Nature Chemistry","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":176,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Manitoba","funders":"Engineering and Physical Sciences Research Council","keywords":"Chemistry; Uranyl; Uranium; Actinide; Silylation; Reactivity (psychology); Molecule; Oxide; Inorganic chemistry; Metal; Covalent bond; Uranium oxide; Crystallography; Photochemistry; Ion; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001781215,0.0004127709,0.0003527414,0.00001940624,0.0002833421,0.0001056696,0.0002622849,0.0006865449,0.003525662],"category_scores_gemma":[0.0001305503,0.0004209146,0.0001004918,0.0001361122,0.0001786568,0.0004269397,0.00009478544,0.001175977,0.00001320536],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002112576,"about_ca_system_score_gemma":0.00004710912,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002585085,"about_ca_topic_score_gemma":8.431487e-7,"domain_scores_codex":[0.9980534,0.0000163464,0.0003441807,0.0005873621,0.0004486619,0.0005500859],"domain_scores_gemma":[0.9987458,0.0001448061,0.000266894,0.0004349154,0.0001266409,0.000280974],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000161369,0.0001236675,0.004857236,0.0003286968,0.0001766817,0.000003923904,0.0005407556,0.000006851546,0.9914927,0.00001838382,0.001093931,0.001195785],"study_design_scores_gemma":[0.001159431,0.000005474466,0.002919519,0.0001467103,0.0001357929,0.00002254859,0.001460443,0.000270373,0.9800007,0.0001459367,0.01322178,0.0005113416],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9702387,0.005173054,0.00003462391,0.0002417435,0.0001333867,0.00008030189,0.0001626255,0.0001617379,0.02377385],"genre_scores_gemma":[0.9954224,0.00008350413,0.0007422003,0.00006355021,0.00180476,0.00002050585,0.0006504653,0.00005624884,0.001156385],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0251837,"threshold_uncertainty_score":0.9998243,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00980491807871153,"score_gpt":0.2481020238356047,"score_spread":0.2382971057568931,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}