{"id":"W2123372163","doi":"10.1139/v03-140","title":"Synthesis and characterization of tantalum(V) metallaheterocycle (Me<sub>2</sub>N)<sub>3</sub> and chloro-mixed-amide (Me<sub>2</sub>N)<sub>3</sub>Ta(Cl)[N(SiMe<sub>3</sub>)<sub>2</sub>]","year":2003,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Trigonal bipyramidal molecular geometry; Amide; Tantalum; Ring (chemistry); Stereochemistry; Crystallography; Metallacycle; Crystal structure; X-ray crystallography; Organic chemistry; Physics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.002338843,0.003449494,0.00486402,0.001463121,0.001558288,0.001256632,0.002444965,0.002304152,0.0006520852],"category_scores_gemma":[0.00205761,0.003888174,0.002293103,0.00233281,0.001824387,0.002054314,0.0005717151,0.002941013,0.0001610582],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.002191609,"about_ca_system_score_gemma":0.002945887,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001461552,"about_ca_topic_score_gemma":0.001909111,"domain_scores_codex":[0.9840795,0.0005715805,0.005271228,0.003374083,0.002733445,0.003970139],"domain_scores_gemma":[0.9844062,0.001058402,0.004726499,0.003089439,0.001446861,0.005272654],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003588928,0.0005699102,0.001684407,0.001794118,0.002514669,0.0007848625,0.0005920216,0.00005700328,0.947052,0.00003185559,0.0006404856,0.04391979],"study_design_scores_gemma":[0.002972101,0.0001892338,0.004671311,0.001664843,0.002746459,0.002552407,0.001203074,0.0002730291,0.9777421,0.0002986134,0.001983922,0.003702907],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9900855,0.003812729,0.0002011784,0.0006245833,0.0008174339,0.0007860503,0.001925909,0.0002549605,0.001491621],"genre_scores_gemma":[0.9901447,0.005828159,0.00009805027,0.0004060091,0.001694609,0.0001922566,0.0007098705,0.0008547191,0.00007158139],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04021689,"threshold_uncertainty_score":0.9997802,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007757898317085789,"score_gpt":0.1821838535323199,"score_spread":0.1744259552152341,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}