{"id":"W2123421866","doi":"10.1139/v02-105","title":"Exploratory synthetic investigations related to 12a-deoxypillaromycinone","year":2002,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Furan; Furfural; Synthon; Intramolecular force; Enone; Catalysis; Adduct; Stereochemistry; Organic chemistry; Medicinal chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002425594,0.0003398607,0.0002225169,0.0001983589,0.0003142965,0.0002623341,0.0002684654,0.0003056705,0.001797069],"category_scores_gemma":[0.00025027,0.0001008497,0.0001826557,0.0002475725,0.0002572926,0.0002784846,0.0002110738,0.0003938126,0.000794127],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003088965,"about_ca_system_score_gemma":0.0003199229,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005507366,"about_ca_topic_score_gemma":0.0006573378,"domain_scores_codex":[0.9998543,0.00003082863,0.000008173325,0.00003208239,0.00003536388,0.00003916344],"domain_scores_gemma":[0.9998943,0.00001552581,0.00002104203,0.00001924388,0.00001985028,0.00002999382],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003194514,0.0002686858,0.0005378679,0.0001634934,0.00000647472,0.0007278586,0.0002152668,0.001051614,0.9853512,0.001228632,0.0001135333,0.01001588],"study_design_scores_gemma":[0.0000529905,0.002252857,0.001313394,0.00001537216,0.00001041654,0.0009324034,0.0001639145,0.0006576423,0.9799647,0.0003180649,0.01430367,0.00001451958],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.985212,0.0009509799,0.003429909,0.0001246872,0.00001745058,0.0001822995,0.0005165871,0.00002996959,0.009536115],"genre_scores_gemma":[0.983907,0.001230108,0.009721495,0.00004276634,0.00001273053,0.00007667176,0.0004515779,0.00001449904,0.004543035],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001797069,"threshold_uncertainty_score":0.006011844,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01889929040107069,"score_gpt":0.190238141438012,"score_spread":0.1713388510369414,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}