{"id":"W2123912274","doi":"10.1002/ejoc.200600226","title":"Diastereoselective [4+3] Cycloadditions of Enantiopure Nitrogen‐Stabilized Oxyallyl Cations","year":2006,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Enantiopure drug; Chemistry; Chelation; Nitrogen; Organic chemistry; Combinatorial chemistry; Medicinal chemistry; Enantioselective synthesis; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003351331,0.0009149807,0.0004013096,0.0003542578,0.0003603684,0.0004282477,0.000583867,0.0003462323,0.003689864],"category_scores_gemma":[0.0001851507,0.000235388,0.000268338,0.0002166073,0.0003513503,0.0003080619,0.0005507027,0.0005463382,0.001334623],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003942304,"about_ca_system_score_gemma":0.0003335006,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006924622,"about_ca_topic_score_gemma":0.00197862,"domain_scores_codex":[0.9997364,0.00004098607,0.00001389739,0.00003723349,0.00003934002,0.0001320973],"domain_scores_gemma":[0.9999048,0.0000144301,0.00002596855,0.00001523736,0.00001247164,0.00002711729],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003573109,0.00006886602,0.0001431528,0.000164369,0.00002008581,0.0005897047,0.0002085389,0.0004163122,0.9891443,0.003149304,0.0009886839,0.004749475],"study_design_scores_gemma":[0.00004932701,0.0002065567,0.0002682726,0.000007199951,0.000012244,0.0001962992,0.00002265612,0.00028672,0.9929394,0.0001312336,0.005864784,0.00001531192],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9612704,0.001343764,0.009300887,0.0002567155,0.0002812308,0.0001547691,0.000720231,0.0004177914,0.02625428],"genre_scores_gemma":[0.9868374,0.001200091,0.003538153,0.00009770467,0.00006724635,0.00006143573,0.0002934319,0.00006554335,0.007838956],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003689864,"threshold_uncertainty_score":0.01234382,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004977069362327835,"score_gpt":0.1807657431075562,"score_spread":0.1757886737452284,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}