{"id":"W2123919968","doi":"10.1139/v04-097","title":"New insights about the hostguest chemistry of the tungsten oxo complex of calix[4]arene, and novel \"one pot\" difunctionalizations of calix[4]arene using tetrachlorometal(VI) oxide (M = Mo, W)","year":2004,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Acetonitrile; Tetrahydrofuran; Uranyl; Lewis acids and bases; Molecule; Aniline; Calixarene; Tungsten; Crystallography; Ligand (biochemistry); Medicinal chemistry; Stereochemistry; Organic chemistry; Solvent; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005554357,0.0002161946,0.0001129277,0.00008871565,0.00008021159,0.0002251388,0.0002053244,0.0002546138,0.001509772],"category_scores_gemma":[0.00006833295,0.00009381306,0.0001231575,0.00006150826,0.0002135106,0.0004081061,0.0002001506,0.0004123325,0.0001293218],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001751393,"about_ca_system_score_gemma":0.0001136251,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002017926,"about_ca_topic_score_gemma":0.0003376664,"domain_scores_codex":[0.9999664,0.000003399137,0.000001501833,0.000007592132,0.00001280672,0.00000837172],"domain_scores_gemma":[0.9999815,0.000003513612,0.000006248703,0.000002637262,0.00000250972,0.000003583206],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000299831,0.00001141859,0.00009969493,0.0000859783,0.000004705706,0.00006288052,0.0000399598,0.0002130729,0.9949074,0.001524086,0.00004925927,0.002971414],"study_design_scores_gemma":[0.00001416995,0.0001870081,0.001370005,0.000009903095,0.00001444648,0.0003366956,0.00007258527,0.001912497,0.987609,0.0009037977,0.007559492,0.00001043658],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9852735,0.001573978,0.00836302,0.0002242098,0.0000289564,0.00001586518,0.00009306494,0.00005901897,0.004368306],"genre_scores_gemma":[0.9928989,0.001286187,0.003181565,0.00009251234,0.00001481677,0.00001230442,0.0001275289,0.00001402336,0.002372144],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001509772,"threshold_uncertainty_score":0.005050719,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03061788673913385,"score_gpt":0.2318442395969302,"score_spread":0.2012263528577963,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}