{"id":"W2123940063","doi":"10.1039/b713933k","title":"Ambient temperature ring-opening polymerisation (ROP) of cyclic chlorophosphazene trimer [N<sub>3</sub>P<sub>3</sub>Cl<sub>6</sub>] catalyzed by silylium ions","year":2007,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":79,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Trimer; Catalysis; Ring (chemistry); Ion; Polymerization; Chemistry; Materials science; Dimer; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007437217,0.0002728426,0.0001497119,0.0000682891,0.00009579033,0.0001518432,0.0001861656,0.0002404094,0.001485151],"category_scores_gemma":[0.0001500233,0.0001309626,0.0002063023,0.00007089889,0.0001875582,0.0002809415,0.0002310524,0.0003479373,0.0003591854],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001146636,"about_ca_system_score_gemma":0.0001477308,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002198217,"about_ca_topic_score_gemma":0.0003690339,"domain_scores_codex":[0.9999443,0.000007318228,0.000003770846,0.00001428915,0.00001048384,0.00001979686],"domain_scores_gemma":[0.9999379,0.0000134627,0.00002521193,0.000008509161,0.000004858557,0.00001003164],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008299699,0.000005945292,0.00004298984,0.00006531168,0.000003593629,0.00006297865,0.00002511459,0.00009831307,0.9977201,0.0001373799,0.00005018013,0.001705035],"study_design_scores_gemma":[0.000006471662,0.0001069092,0.0004377754,0.000002844756,0.000003723799,0.0001114957,0.000007319792,0.0002205906,0.998198,0.00003447334,0.0008675301,0.00000298081],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9900646,0.001076728,0.00415891,0.00006079741,0.00002068341,0.00003246282,0.0001492457,0.0001472215,0.004289525],"genre_scores_gemma":[0.9953621,0.0005401308,0.002297808,0.00001401796,0.000005822204,0.00002019406,0.0001068429,0.00002838702,0.001624597],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001485151,"threshold_uncertainty_score":0.004968286,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01078284750469809,"score_gpt":0.2403954092240522,"score_spread":0.2296125617193541,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}