{"id":"W2124295521","doi":"10.1021/jo0481351","title":"Copper-Promoted <i>N</i>-Arylations of Cyclic Imides within Six-Membered Rings:  A Facile Route to Arylene-Based Organic Materials","year":2005,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Arylene; Imide; Copper; Chemistry; Amine gas treating; Perylene; Polymer chemistry; Organic chemistry; Combinatorial chemistry; Aryl; Molecule","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006595872,0.0003418489,0.0005820555,0.00006465299,0.000202203,0.00008957829,0.0008351713,0.0002149896,0.008159371],"category_scores_gemma":[0.0006931901,0.0002832113,0.0001841302,0.0004372886,0.000168897,0.0001728079,0.0001516893,0.0005379078,0.00007919602],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004715287,"about_ca_system_score_gemma":0.0005820258,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004795258,"about_ca_topic_score_gemma":0.00004574588,"domain_scores_codex":[0.997482,0.000006046945,0.001330057,0.0002495638,0.0005655385,0.000366791],"domain_scores_gemma":[0.997022,0.0002992927,0.00117778,0.0008671572,0.0003915509,0.0002422406],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001839995,0.0002177376,0.0002651996,0.0001779157,0.0001450998,0.000008295273,0.0008261782,0.00114404,0.9964885,8.337822e-7,0.0004536597,0.0000885709],"study_design_scores_gemma":[0.001221437,0.00002726052,0.000233757,0.0002588851,0.000292093,0.0005850818,0.0006273136,0.0001182492,0.9959762,0.00003014188,0.0003538259,0.0002757913],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978463,0.000150926,0.0001034007,0.001129059,0.0001227798,0.0001065173,0.0001591644,0.00007471027,0.0003071488],"genre_scores_gemma":[0.9980749,0.00002064182,0.0003075196,0.00008238259,0.0005055804,0.000004182837,0.00003805576,0.00008188654,0.0008848388],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008080175,"threshold_uncertainty_score":0.999962,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01112087170207926,"score_gpt":0.2444247569561946,"score_spread":0.2333038852541154,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}