{"id":"W2124396901","doi":"10.1002/chem.201101252","title":"Direct Synthesis of Aryl Ketones by Palladium‐Catalyzed Desulfinative Addition of Sodium Sulfinates to Nitriles","year":2011,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":119,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Sulfinic acid; Aryl; Palladium; Chemistry; Catalysis; Sodium; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0009945761,0.000421982,0.000646077,0.0001271457,0.0001312351,0.00003923022,0.0009493554,0.000118747,0.003833516],"category_scores_gemma":[0.001987122,0.0004061794,0.0003373191,0.0002633635,0.0003078359,0.0001671785,0.0001575435,0.0003896609,0.00003120171],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001147043,"about_ca_system_score_gemma":0.0001038839,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001502949,"about_ca_topic_score_gemma":4.594517e-7,"domain_scores_codex":[0.9975247,0.0001169268,0.001026257,0.0004388808,0.0004608897,0.0004323785],"domain_scores_gemma":[0.997088,0.0005332801,0.0009796955,0.0006203337,0.0004555909,0.0003231427],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003384399,0.0003567366,0.0005530561,0.0002790589,0.0001749104,0.00008725726,0.0004959902,4.437809e-7,0.9858072,0.000003174678,0.005420574,0.006483104],"study_design_scores_gemma":[0.0004150406,0.00004278626,0.0004513705,0.0008249885,0.0001265577,0.0001083908,0.0005453254,0.000007547599,0.9959543,0.00009515363,0.00102968,0.0003988488],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9365781,0.0003747376,0.0001988893,0.00004009128,0.00003467897,0.0000704483,0.0005061641,0.0001426762,0.06205424],"genre_scores_gemma":[0.9962887,0.0001663333,0.002762991,0.00001568358,0.0001625171,0.00002078738,0.00004658467,0.0001083627,0.0004280733],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06162617,"threshold_uncertainty_score":0.999839,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01971264019179046,"score_gpt":0.2163935945862965,"score_spread":0.196680954394506,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}