{"id":"W2124404091","doi":"10.1039/b709193a","title":"Temperature dependence of the NO3 absorption cross-section above 298 K and determination of the equilibrium constant for NO3 + NO2↔ N2O5 at atmospherically relevant conditions","year":2007,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":76,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"National Oceanic and Atmospheric Administration","keywords":"Constant (computer programming); Absorption (acoustics); Absorption cross section; Thermodynamics; Section (typography); Equilibrium constant; Cross section (physics); Chemistry; Analytical Chemistry (journal); Physics; Environmental chemistry; Optics; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000116772,0.0002132892,0.0002654188,7.418309e-7,0.0001650841,0.00002737309,0.0003127009,0.0001672554,0.00006226125],"category_scores_gemma":[0.0001615333,0.0001424798,0.0002216196,0.0002529186,0.0007445206,0.0001475868,0.00007666222,0.0002973166,0.000001486972],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003283296,"about_ca_system_score_gemma":0.00005955721,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002486362,"about_ca_topic_score_gemma":0.000004404189,"domain_scores_codex":[0.9986253,0.00001498329,0.0003569913,0.0003477183,0.0003729758,0.0002820732],"domain_scores_gemma":[0.9985934,0.0004511415,0.000346499,0.0003297113,0.0001771194,0.000102073],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001045864,0.0001000041,0.005875128,0.000205976,0.00001377695,3.926111e-7,0.00008297,0.0002173137,0.9927462,0.00002846127,0.00005468358,0.0005705033],"study_design_scores_gemma":[0.0003884561,0.00002446204,0.009189749,0.00006178813,0.00004386532,0.0000114906,0.00003767584,0.004840525,0.9833201,0.001840339,0.00006686874,0.0001747055],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.997186,0.0000298073,0.0004126686,0.00008315458,0.00009095508,0.0002418714,0.0003005321,0.00001999724,0.001635025],"genre_scores_gemma":[0.9987472,0.000003738278,0.0004514613,0.00004739055,0.000430729,0.000004718486,0.00009532436,0.000008436936,0.0002109424],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00942613,"threshold_uncertainty_score":0.5810156,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008549698497507401,"score_gpt":0.2376176834797679,"score_spread":0.2290679849822606,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}