{"id":"W2125142653","doi":"10.1093/chromsci/44.6.333","title":"Development of an Impregnated Reagent and Automation of Solid-Phase Analytical Derivatization for Carbonyls: Proof of Principle","year":2006,"lang":"en","type":"article","venue":"Journal of Chromatographic Science","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Derivatization; Chemistry; Reagent; Chromatography; Aqueous solution; Sample preparation; Extraction (chemistry); Solid phase extraction; Aqueous two-phase system; High-performance liquid chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007657491,0.0001418716,0.0004253549,0.0003769421,0.00008816525,0.00001638467,0.0003297256,0.00009831425,0.00002536291],"category_scores_gemma":[0.0002075278,0.000120197,0.0001455066,0.001076755,0.0007843733,0.0003002598,0.00004342811,0.00008680136,2.180057e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003199279,"about_ca_system_score_gemma":0.0003755633,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004402278,"about_ca_topic_score_gemma":0.000002870293,"domain_scores_codex":[0.9975798,0.00001221001,0.001288215,0.0002014555,0.0007102565,0.0002081163],"domain_scores_gemma":[0.9972014,0.00006942074,0.001589392,0.0002119849,0.0007832427,0.0001445731],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008100126,0.0006355761,0.00472941,0.0007245747,0.00006395885,0.000002083566,0.0001869917,0.0001447464,0.9916312,0.0007997509,0.000006932099,0.0009938219],"study_design_scores_gemma":[0.001148841,0.000167604,0.005760966,0.0003396852,0.00009465613,0.00003766963,0.0001610145,0.0300136,0.9613881,0.0007441411,0.00002729863,0.0001164283],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991622,0.0001087328,0.007860463,0.00001269369,0.0000175911,0.00008468253,0.00001540273,0.000009282401,0.0002691014],"genre_scores_gemma":[0.9854378,0.000007727064,0.01450083,0.000002496435,0.00002556718,0.000003387612,0.000008872377,0.000007993718,0.000005332248],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03024306,"threshold_uncertainty_score":0.4901492,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01547489232004786,"score_gpt":0.3268614485084501,"score_spread":0.3113865561884023,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}