{"id":"W2125167487","doi":"10.1039/c4dt02100b","title":"Cationic iridium(<scp>iii</scp>) complexes bearing ancillary 2,5-dipyridyl(pyrazine) (2,5-dpp) and 2,2′:5′,2′′-terpyridine (2,5-tpy) ligands: synthesis, optoelectronic characterization and light-emitting electrochemical cells","year":2014,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Iridium; Terpyridine; Chemistry; Cyclic voltammetry; Acetonitrile; Photochemistry; Electrochemistry; Cationic polymerization; Quantum yield; Hexafluorophosphate; Electroluminescence; Pyrazine; Excited state; Ligand (biochemistry); Photoluminescence; Physical chemistry; Stereochemistry; Materials science; Polymer chemistry; Fluorescence; Organic chemistry; Catalysis; Metal; Optoelectronics; Electrode","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002887597,0.0004209703,0.0003097423,0.0002047217,0.0001868485,0.0004322533,0.0006031865,0.0005333236,0.0009718359],"category_scores_gemma":[0.000379205,0.000261745,0.0001327279,0.0003889463,0.0002075316,0.0002597621,0.0002601676,0.0003737659,0.0003172582],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003777423,"about_ca_system_score_gemma":0.0001855101,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004466552,"about_ca_topic_score_gemma":0.0007304275,"domain_scores_codex":[0.9997526,0.00004153066,0.00002588573,0.00005851258,0.00007594973,0.00004565242],"domain_scores_gemma":[0.9998822,0.000018156,0.00003429021,0.00001357616,0.00003175893,0.00002005383],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007794699,0.00001796079,0.00005224502,0.00007144916,0.000003279019,0.00002749419,0.00001306757,0.0001608594,0.9981514,0.0001066592,0.00004510417,0.001272459],"study_design_scores_gemma":[0.00001755704,0.0001898789,0.0004262087,0.000003576589,0.000007680832,0.0001173124,0.000008568385,0.0006647131,0.9976306,0.00001787411,0.000910071,0.000005815784],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9911966,0.0008847743,0.005530902,0.00006226562,0.0000169777,0.00007701195,0.0002713091,0.0001320616,0.001828108],"genre_scores_gemma":[0.9871372,0.0005871028,0.009919841,0.00003397895,0.000008403253,0.00009704168,0.0003254002,0.00002863072,0.001862423],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009718359,"threshold_uncertainty_score":0.003251076,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005616698147561486,"score_gpt":0.2006545358513931,"score_spread":0.1950378377038317,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}