{"id":"W2125167487","doi":"10.1039/c4dt02100b","title":"Cationic iridium(<scp>iii</scp>) complexes bearing ancillary 2,5-dipyridyl(pyrazine) (2,5-dpp) and 2,2′:5′,2′′-terpyridine (2,5-tpy) ligands: synthesis, optoelectronic characterization and light-emitting electrochemical cells","year":2014,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Iridium; Terpyridine; Chemistry; Cyclic voltammetry; Acetonitrile; Photochemistry; Electrochemistry; Cationic polymerization; Quantum yield; Hexafluorophosphate; Electroluminescence; Pyrazine; Excited state; Ligand (biochemistry); Photoluminescence; Physical chemistry; Stereochemistry; Materials science; Polymer chemistry; Fluorescence; Organic chemistry; Catalysis; Metal; Optoelectronics; Electrode","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005379743,0.0004980099,0.0005582952,0.0003578341,0.0005207628,0.0002839456,0.0002906875,0.0002957141,0.00003084213],"category_scores_gemma":[0.000146401,0.0005520785,0.0001037994,0.0006033837,0.0001233471,0.0005234149,0.00003657725,0.0008109711,0.00003590069],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002664701,"about_ca_system_score_gemma":0.00008912537,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003097963,"about_ca_topic_score_gemma":0.00003350324,"domain_scores_codex":[0.9971348,0.00008243554,0.0006356689,0.000701094,0.0004204048,0.001025567],"domain_scores_gemma":[0.9982019,0.0007234255,0.000113259,0.0004743502,0.0001241475,0.0003628886],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008118403,0.00005385486,0.0001990601,0.0002960431,0.0001273108,0.000001954989,0.0005690351,0.0000679057,0.9960853,0.00008376592,0.0001031613,0.002404521],"study_design_scores_gemma":[0.0005513289,0.00007671236,0.0009120927,0.0001179777,0.0001215757,0.00007366574,0.00007989177,0.0354974,0.9551286,0.00002003338,0.007125651,0.0002951211],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.909776,0.001063059,0.08684263,0.0003346944,0.0002471778,0.0004742035,0.00003976281,0.0007721449,0.0004503524],"genre_scores_gemma":[0.9961168,0.002123164,0.0007322149,0.00005762613,0.0003528677,0.0001159395,0.0001001248,0.0001563009,0.0002449584],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08634083,"threshold_uncertainty_score":0.9996931,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005616698147561486,"score_gpt":0.2006545358513931,"score_spread":0.1950378377038317,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}