{"id":"W2125238509","doi":"10.1139/v05-105","title":"Alkylcobalt carbonyls. Part XIV. Generation of chiral conformations by centers of chirality in organocobalt complexes","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Crystal structures of chemical compounds","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Isopropyl; Chirality (physics); Intramolecular force; Stereochemistry; Crystallography; Crystal structure; NMR spectra database; Proton NMR; Spectral line; Medicinal chemistry; Chiral symmetry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000135024,0.0003088288,0.0002062767,0.0001312972,0.0002227236,0.0002931179,0.0003375479,0.0001921617,0.002389107],"category_scores_gemma":[0.0002628864,0.0001344004,0.0001285279,0.0002062016,0.0002881174,0.0001999904,0.0002786187,0.0003581982,0.0004987358],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004282215,"about_ca_system_score_gemma":0.000209281,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005930346,"about_ca_topic_score_gemma":0.00126956,"domain_scores_codex":[0.9998693,0.00001729484,0.000006736169,0.00002432367,0.00004349267,0.00003876427],"domain_scores_gemma":[0.9998808,0.00001926904,0.00004243013,0.00001329128,0.00001455816,0.00002968755],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004448115,0.00008202084,0.0002824363,0.0002272532,0.00002086572,0.0001506602,0.0001175378,0.0007798868,0.9906766,0.001778061,0.0004801422,0.004959689],"study_design_scores_gemma":[0.0001388874,0.0004925253,0.0008995616,0.00001233339,0.00002132169,0.0001721526,0.00003655144,0.000865399,0.9890184,0.0001665708,0.008162596,0.00001360924],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9898561,0.001283671,0.002019303,0.00007858623,0.00003822536,0.00004587052,0.0001702542,0.00008183881,0.006426077],"genre_scores_gemma":[0.9940426,0.0007654472,0.00135453,0.00006431843,0.000009921127,0.00004048281,0.0002771346,0.0000257034,0.003419901],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002389107,"threshold_uncertainty_score":0.007992327,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01333050719033321,"score_gpt":0.2185034767762508,"score_spread":0.2051729695859176,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}