{"id":"W2125505293","doi":"10.1021/jo052295a","title":"Ruthenium-Catalyzed [2+2] Cycloadditions of Alkynyl Sulfides and Alkynyl Sulfones","year":2006,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":95,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Cyclobutene; Chemistry; Cycloaddition; Ruthenium; Sulfone; Catalysis; Bicyclic molecule; Sulfide; Medicinal chemistry; Cycloalkene; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002315016,0.0005525042,0.0002791215,0.0002498571,0.0001651319,0.0002249712,0.0002302943,0.0002274702,0.001683735],"category_scores_gemma":[0.0001888945,0.0001915388,0.0001981804,0.0002346485,0.000215901,0.0002607196,0.0002003886,0.0003098013,0.0003813377],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002616282,"about_ca_system_score_gemma":0.0002596098,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004160146,"about_ca_topic_score_gemma":0.001435375,"domain_scores_codex":[0.9998285,0.00003199284,0.00001362798,0.00002183858,0.00004331059,0.00006087047],"domain_scores_gemma":[0.9999075,0.0000229124,0.0000261497,0.00001256714,0.00001422705,0.00001675933],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001974622,0.00004075718,0.0001521544,0.0001080069,0.0000155591,0.0003707162,0.00006115542,0.0005318616,0.9940148,0.001052702,0.0001494872,0.0033054],"study_design_scores_gemma":[0.0000203995,0.0002586192,0.0004801036,0.000003935714,0.00001058914,0.0001458519,0.00001564397,0.0003345811,0.99707,0.0000684391,0.001585831,0.000005993759],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9818348,0.001438052,0.004063582,0.00007799098,0.00006124841,0.00008686892,0.0001700979,0.00006667722,0.01220066],"genre_scores_gemma":[0.9939947,0.0009285232,0.001819679,0.00002219726,0.00001051259,0.00003045313,0.0001146396,0.00001331677,0.003066046],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001683735,"threshold_uncertainty_score":0.005632699,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004977977868711425,"score_gpt":0.1956479063183169,"score_spread":0.1906699284496055,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}