{"id":"W2125521158","doi":"10.1002/chem.200902694","title":"Diastereoselective Benzylic Arylation of Tetralins","year":2009,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Enantiopure drug; Tetralin; Chemistry; Scope (computer science); Aryl; Substrate (aquarium); Intermolecular force; Organic chemistry; Combinatorial chemistry; Catalysis; Computer science; Molecule; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006876956,0.0002876059,0.0003237597,0.00003062509,0.0001271643,0.00006288003,0.0005448841,0.00008886499,0.004520406],"category_scores_gemma":[0.0004592941,0.0002873002,0.0002198622,0.0001985551,0.0001022957,0.000106866,0.00005230293,0.0007256297,0.00002670113],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001366144,"about_ca_system_score_gemma":0.0001009462,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":6.267013e-7,"about_ca_topic_score_gemma":3.99188e-8,"domain_scores_codex":[0.9981169,0.0000921941,0.0007103003,0.0003296464,0.0003718014,0.000379125],"domain_scores_gemma":[0.9984099,0.0001082482,0.0005450563,0.0004851223,0.0001738657,0.0002778671],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004345175,0.0001352681,0.0002661156,0.00006730967,0.0000583794,0.00009042589,0.0003275832,0.00001045333,0.9660175,0.000003101173,0.0003093266,0.03267105],"study_design_scores_gemma":[0.0008393688,0.00003319723,0.001335241,0.0001742126,0.00007324917,0.001294296,0.0002794199,0.0001772597,0.9931632,0.0002307745,0.002108985,0.0002907728],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8725051,0.0002352912,0.001162046,0.0001720253,0.00006186611,0.00002353092,0.00001409986,0.00007723841,0.1257488],"genre_scores_gemma":[0.9934854,0.00004547338,0.003476682,0.00003907955,0.0008815557,5.020821e-7,0.00001279737,0.00004954435,0.002008965],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1237399,"threshold_uncertainty_score":0.9999579,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01618685709161303,"score_gpt":0.2494792651176765,"score_spread":0.2332924080260635,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}