{"id":"W2125521158","doi":"10.1002/chem.200902694","title":"Diastereoselective Benzylic Arylation of Tetralins","year":2009,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Enantiopure drug; Tetralin; Chemistry; Scope (computer science); Aryl; Substrate (aquarium); Intermolecular force; Organic chemistry; Combinatorial chemistry; Catalysis; Computer science; Molecule; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003492586,0.0005837654,0.0003747206,0.0003407487,0.0003023798,0.0001964423,0.0005620592,0.000278452,0.005115881],"category_scores_gemma":[0.0003061788,0.0002548336,0.000275133,0.0004264755,0.0001853399,0.0004329195,0.0006071184,0.0009272449,0.002647441],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004211241,"about_ca_system_score_gemma":0.0003250842,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004476375,"about_ca_topic_score_gemma":0.001498437,"domain_scores_codex":[0.9996662,0.00004630136,0.00004009786,0.00006213712,0.00005817536,0.0001271355],"domain_scores_gemma":[0.9998834,0.00001431315,0.00002952359,0.00003068004,0.00002503728,0.00001704326],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002345325,0.00008649828,0.0002442854,0.0004072389,0.00003640843,0.0004273989,0.0002542549,0.0006489027,0.9736122,0.002865935,0.002648184,0.01853405],"study_design_scores_gemma":[0.0000339496,0.0002328149,0.0004194642,0.00001706829,0.00001725408,0.000399711,0.00002368907,0.0007424187,0.9793562,0.0001582059,0.01858449,0.00001464201],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8482091,0.00467423,0.06494167,0.000547258,0.0004235273,0.0003552518,0.003761806,0.001430692,0.07565634],"genre_scores_gemma":[0.9618387,0.004226594,0.01810228,0.0001857043,0.00004653011,0.0001580408,0.002026612,0.0003056378,0.01310987],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005115881,"threshold_uncertainty_score":0.01711428,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01618685709161303,"score_gpt":0.2494792651176765,"score_spread":0.2332924080260635,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}