{"id":"W2125527045","doi":"10.1002/anie.200604034","title":"A Tetrahedral Organophosphonate as a Linker for a Microporous Copper Framework","year":2006,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":119,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Diamondoid; Microporous material; Linker; Sorption; Phosphonate; Copper; Ligand (biochemistry); Cluster (spacecraft); Chemistry; Materials science; Crystallography; Combinatorial chemistry; Topology (electrical circuits); Computer science; Molecule; Organic chemistry; Mathematics; Computer network; Combinatorics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001134077,0.0002449474,0.0002144054,0.00006067224,0.0001563658,0.0001284516,0.0003566976,0.0003650293,0.007416625],"category_scores_gemma":[0.000328577,0.0002454199,0.0002031896,0.0001425216,0.00008625622,0.0001654381,0.00005409435,0.0002995896,0.000247347],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001898118,"about_ca_system_score_gemma":0.00006957953,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001223112,"about_ca_topic_score_gemma":0.00001194423,"domain_scores_codex":[0.9984467,0.000005137231,0.0004171118,0.0004607258,0.0003736989,0.0002966392],"domain_scores_gemma":[0.9987935,0.0002953876,0.0002141903,0.0003147455,0.00029915,0.00008302724],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009813215,0.0003552822,0.0002730903,0.000051174,0.0001149193,0.000007147567,0.0000807227,0.00001010016,0.8748698,0.01422082,0.1085849,0.00133392],"study_design_scores_gemma":[0.0003734434,0.00001235305,0.00009814387,0.0001066448,0.00004088507,0.00002397429,0.00005789093,0.00005780862,0.7695734,0.03311399,0.1963136,0.0002278542],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6520701,0.001902917,0.1441783,0.02216576,0.005541491,0.001181456,0.003440898,0.001216899,0.1683021],"genre_scores_gemma":[0.9763398,0.00008550415,0.007786746,0.0007261845,0.004294266,0.0003890917,0.001831328,0.00006904162,0.008478033],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3242697,"threshold_uncertainty_score":0.9999998,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01019978128518651,"score_gpt":0.2531333666744132,"score_spread":0.2429335853892267,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}