{"id":"W2125598210","doi":"10.1002/9781119953678.rad066","title":"Persistent and Stable Silyl Radicals","year":2012,"lang":"en","type":"other","venue":"","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Israel Science Foundation; Ministère de l'Économie, de la Science et de l'Innovation - Québec","keywords":"Silylation; Radical; Electron paramagnetic resonance; Chemistry; Substituent; Photochemistry; Organic chemistry; Catalysis; Nuclear magnetic resonance","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003044173,0.0003748948,0.0001725757,0.0003997946,0.0002157726,0.0005435473,0.0002881273,0.0003785843,0.003684592],"category_scores_gemma":[0.0002119918,0.00009579599,0.0001510172,0.00023135,0.0004000076,0.0007931413,0.0004291935,0.0006269469,0.0007814298],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002862378,"about_ca_system_score_gemma":0.0001857654,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001075241,"about_ca_topic_score_gemma":0.0002101729,"domain_scores_codex":[0.9998181,0.00002250677,0.00001140428,0.00005012091,0.00007131094,0.00002651926],"domain_scores_gemma":[0.999806,0.00004014797,0.00006311701,0.00001970432,0.00004571982,0.00002529328],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001704954,0.0000339514,0.0004621274,0.001335993,0.00003052249,0.0002737304,0.0001503126,0.0002735568,0.9196424,0.02284112,0.002167525,0.05261832],"study_design_scores_gemma":[0.00002534532,0.0003884781,0.0007642068,0.00007216258,0.00003819402,0.0004185818,0.00008177169,0.0005609572,0.8840391,0.003889905,0.1097019,0.00001938529],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6077034,0.2212609,0.07251938,0.002057447,0.001985404,0.0001505942,0.001046549,0.0007172448,0.09255912],"genre_scores_gemma":[0.9166974,0.03430752,0.01397134,0.0004693322,0.0005308096,0.00006919092,0.0005007444,0.0001003606,0.03335331],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003684592,"threshold_uncertainty_score":0.01232612,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01592638797635366,"score_gpt":0.2110437303720564,"score_spread":0.1951173423957028,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}