{"id":"W2126043629","doi":"10.1002/chin.201206027","title":"ChemInform Abstract: Carbon—Carbon Bond‐Forming Reactions of α‐Carbonyl Carbocations: Exploration of a Reversed‐Polarity Equivalent of Enolate Chemistry.","year":2012,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Carbocation; Nucleophile; Carbon fibers; Photochemistry; Polarity (international relations); Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001776457,0.0004055887,0.00009252042,0.0002409489,0.0001768658,0.0002260073,0.0003223194,0.0002162958,0.007239769],"category_scores_gemma":[0.0001253993,0.0001214123,0.0001191116,0.0001564866,0.0002330872,0.0002977165,0.0002050583,0.0004140302,0.001610746],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002469768,"about_ca_system_score_gemma":0.0003404159,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004526273,"about_ca_topic_score_gemma":0.0006739933,"domain_scores_codex":[0.9999399,0.000008683646,0.000002843713,0.00001444942,0.00001833644,0.00001567254],"domain_scores_gemma":[0.9999702,0.000004476407,0.000005781476,0.00000392152,0.000005952941,0.000009696621],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005964169,0.0001756758,0.0003573913,0.000455846,0.00002741389,0.000360023,0.0001095451,0.0006694687,0.9396215,0.01535123,0.003866201,0.03840915],"study_design_scores_gemma":[0.0001528453,0.0007231479,0.0005112537,0.0000237672,0.00001900193,0.0005736099,0.00002881048,0.000871899,0.9556744,0.0007101226,0.04069252,0.00001845507],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7446635,0.009334846,0.05220332,0.001477066,0.000580832,0.0004026822,0.001987035,0.001183707,0.1881671],"genre_scores_gemma":[0.9697299,0.003697764,0.01016757,0.0001984335,0.00004318047,0.00005297302,0.0007379451,0.00005643575,0.01531576],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007239769,"threshold_uncertainty_score":0.02421939,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04963448446895999,"score_gpt":0.2976918078910603,"score_spread":0.2480573234221003,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}