{"id":"W2126134968","doi":"10.1139/v01-019","title":"Dithiophosphinates of gold (I); oxidative addition of Cl<sub>2</sub> to a neutral, dinuclear gold(I) dithiophosphinate complex, and X-ray crystal structures of [AuS<sub>2</sub>P(C<sub>2</sub>H<sub>5</sub>)<sub>2</sub>]<sub>2</sub>, [AuS<sub>2</sub>PPh<sub>2</sub>]<sub>2</sub>, Au<sub>2</sub>(CH<sub>2</sub>)<sub>2</sub>PMe<sub>2</sub>(S<sub>2</sub>PPh<sub>2</sub>), and Au<sub>2</sub>Cl<sub>2</sub>[(CH<sub>2</sub>)<sub>2</sub>PMe<sub>2</sub>][S<sub>2</sub>PPh<sub>2</sub>]","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Crystallography; Crystal structure; Moiety; Ligand (biochemistry); Oxidative addition; Stereochemistry; Ylide; Oxidation state; Intermolecular force; Molecule; Metal; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity"],"category_scores_codex":[0.02717344,0.05155949,0.04926765,0.02772854,0.0210708,0.0171803,0.0353241,0.03456325,0.0008993723],"category_scores_gemma":[0.0170324,0.06067418,0.02912487,0.04095154,0.02880564,0.02869125,0.01871833,0.04861457,0.006773104],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.03642244,"about_ca_system_score_gemma":0.03327254,"about_ca_topic_candidate":true,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001801421,"about_ca_topic_score_gemma":0.02116477,"domain_scores_codex":[0.8196751,0.01427528,0.04905984,0.04000016,0.0323425,0.04464711],"domain_scores_gemma":[0.8446504,0.01535107,0.04766561,0.03092664,0.02308322,0.03832302],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.01898165,0.01520914,0.004128422,0.01573063,0.02033174,0.01322964,0.009001279,0.005588443,0.772226,0.0007864227,0.04325083,0.08153584],"study_design_scores_gemma":[0.04311432,0.008626495,0.01357793,0.02027639,0.01947228,0.01492729,0.009030587,0.003503427,0.8095882,0.004544089,0.005518516,0.04782046],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8794403,0.01664895,0.002199358,0.005210956,0.01879529,0.02738549,0.03902557,0.00966274,0.001631324],"genre_scores_gemma":[0.8471494,0.07033795,0.001004653,0.006482223,0.02101845,0.009005763,0.02742407,0.01743221,0.0001452212],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.053689,"threshold_uncertainty_score":0.9966964,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009650524156577356,"score_gpt":0.1980930549049514,"score_spread":0.1884425307483741,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}