{"id":"W2126134968","doi":"10.1139/v01-019","title":"Dithiophosphinates of gold (I); oxidative addition of Cl<sub>2</sub> to a neutral, dinuclear gold(I) dithiophosphinate complex, and X-ray crystal structures of [AuS<sub>2</sub>P(C<sub>2</sub>H<sub>5</sub>)<sub>2</sub>]<sub>2</sub>, [AuS<sub>2</sub>PPh<sub>2</sub>]<sub>2</sub>, Au<sub>2</sub>(CH<sub>2</sub>)<sub>2</sub>PMe<sub>2</sub>(S<sub>2</sub>PPh<sub>2</sub>), and Au<sub>2</sub>Cl<sub>2</sub>[(CH<sub>2</sub>)<sub>2</sub>PMe<sub>2</sub>][S<sub>2</sub>PPh<sub>2</sub>]","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Crystallography; Crystal structure; Moiety; Ligand (biochemistry); Oxidative addition; Stereochemistry; Ylide; Oxidation state; Intermolecular force; Molecule; Metal; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006281416,0.0002953584,0.0001381709,0.00009794255,0.0001244943,0.0001488826,0.0003455858,0.0001770737,0.001136435],"category_scores_gemma":[0.0001210632,0.0002016215,0.00007955822,0.0001783181,0.000239424,0.0001335437,0.0002743076,0.0002695588,0.0001977203],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004332795,"about_ca_system_score_gemma":0.0002294831,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002475754,"about_ca_topic_score_gemma":0.004669548,"domain_scores_codex":[0.9999329,0.000007072684,0.000004559166,0.000022302,0.0000197178,0.00001351291],"domain_scores_gemma":[0.999961,0.000006274683,0.00001258356,0.000007184176,0.000006288689,0.000006555812],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001561252,0.000007063548,0.0001758142,0.0001157892,0.000009848361,0.00008388919,0.00006374314,0.0002284513,0.9975581,0.0002305056,0.00006832656,0.001302329],"study_design_scores_gemma":[0.000008158996,0.00006477389,0.0005018383,0.000002666891,0.000005450542,0.00007498926,0.00002420301,0.0001861549,0.9980007,0.0000346782,0.001094117,0.00000220421],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9894235,0.0008750532,0.003623518,0.00005438775,0.00001455102,0.00004087175,0.000286625,0.0001760638,0.005505592],"genre_scores_gemma":[0.9949328,0.0004565086,0.001818883,0.00002090959,0.000001856017,0.0000189459,0.0003136607,0.00002096603,0.002415394],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002475754,"threshold_uncertainty_score":0.004922628,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009650524156577356,"score_gpt":0.1980930549049514,"score_spread":0.1884425307483741,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}