{"id":"W2126141837","doi":"10.1039/b923910c","title":"Novel carbon-centred reactivity of [(H)C(PPh2Se)2]− in the formation of structurally diverse Sn(iv), Te(iv) and Hg(ii) complexes of the triseleno ligand [(Se)C(PPh2Se)2]2–","year":2010,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Homoleptic; Chemistry; Reactivity (psychology); Molar ratio; Ligand (biochemistry); Selenium; Yield (engineering); Medicinal chemistry; Carbon fibers; Stereochemistry; Catalysis; Metal; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001091826,0.0002805673,0.000132903,0.0001013348,0.0001294453,0.000441618,0.0002839933,0.0003032193,0.0009855602],"category_scores_gemma":[0.0001503822,0.0001549298,0.00009335418,0.00009012454,0.0002696092,0.0002089701,0.0002248981,0.0002539023,0.0001954541],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002442351,"about_ca_system_score_gemma":0.0001676392,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003830702,"about_ca_topic_score_gemma":0.001273825,"domain_scores_codex":[0.999921,0.0000134264,0.000004984289,0.0000207746,0.00002078745,0.00001904931],"domain_scores_gemma":[0.9999516,0.00001047644,0.000009045839,0.000008376363,0.000007281162,0.00001323028],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001053122,0.00001060942,0.0001172822,0.00003447367,0.000006341297,0.00007797523,0.00002815027,0.0001654201,0.9978647,0.0003494342,0.000055432,0.001184976],"study_design_scores_gemma":[0.0000117765,0.0000949511,0.0004694934,0.000001268571,0.000005284706,0.0001688028,0.00001151813,0.0004579132,0.9978341,0.00005422822,0.000885892,0.000004765996],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9950465,0.0002438502,0.001395925,0.00003043879,0.00001060999,0.00001530246,0.00006285172,0.00006988457,0.003124679],"genre_scores_gemma":[0.9981506,0.00008219493,0.000768257,0.00001462423,0.000002277981,0.000005737439,0.00006318473,0.00001165774,0.0009013213],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009855602,"threshold_uncertainty_score":0.003297031,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03900939241813443,"score_gpt":0.2507786193482174,"score_spread":0.211769226930083,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}