{"id":"W2126528344","doi":"10.1016/j.apcata.2009.06.032","title":"An investigation of carbon-supported CuCl2/PdCl2 catalysts for diethyl carbonate synthesis","year":2009,"lang":"en","type":"article","venue":"Applied Catalysis A General","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":52,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"Partenariat Canadien Contre Le Cancer","keywords":"Catalysis; Palladium; X-ray absorption fine structure; Chemistry; Selectivity; Copper; Inorganic chemistry; Copper chloride; Diethyl carbonate; Nuclear chemistry; XANES; Carbonate; Organic chemistry; Physical chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003383673,0.0003757614,0.0002831025,0.0003680084,0.0004410307,0.0007091096,0.0007467382,0.000598389,0.001312266],"category_scores_gemma":[0.0006679008,0.0002490584,0.0001878477,0.0002821901,0.0003733469,0.0004550362,0.0002744808,0.0004303897,0.0003172026],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009268585,"about_ca_system_score_gemma":0.000453864,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004770701,"about_ca_topic_score_gemma":0.007216197,"domain_scores_codex":[0.9996501,0.00004481314,0.00002705143,0.00004584498,0.0001531486,0.00007909368],"domain_scores_gemma":[0.9998274,0.00005746751,0.00002187124,0.00002343047,0.00004861494,0.00002112443],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006289495,0.0001028842,0.0006693399,0.0005611927,0.00002628768,0.0003082913,0.00009751951,0.0004702279,0.9880174,0.0006875828,0.0003600188,0.00807029],"study_design_scores_gemma":[0.00002318298,0.000269063,0.0009255334,0.000008188779,0.00001653998,0.0001565928,0.00004586772,0.001772974,0.9939825,0.00003744921,0.002752224,0.000009751516],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9853742,0.004054863,0.0015103,0.0002275446,0.00006463566,0.00009437955,0.0002535966,0.00008918529,0.008331393],"genre_scores_gemma":[0.9975222,0.0006951779,0.0006723953,0.00002341656,0.000009710742,0.00001208065,0.0001415854,0.00001252885,0.000910842],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004770701,"threshold_uncertainty_score":0.009485841,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01166431967137121,"score_gpt":0.2406579313254633,"score_spread":0.2289936116540921,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}