{"id":"W2126623690","doi":"10.1021/jo991696l","title":"Synthesis of Glycophostones:  Cyclic Phosphonate Analogues of Biologically Relevant Sugars","year":2000,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Anomer; Neuraminic acid; Phosphonate; Chemistry; Carbon atom; Fucose; Stereochemistry; Glucosamine; Organic chemistry; Biochemistry; Galactose; Sialic acid; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006270692,0.0002964346,0.0007797619,0.00002453052,0.00007253913,0.00001145838,0.001034935,0.0002843893,0.02455195],"category_scores_gemma":[0.0007620953,0.0001996876,0.0004030774,0.0002992793,0.0004379165,0.00006572105,0.00007717125,0.0004612998,0.00001237841],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008888376,"about_ca_system_score_gemma":0.000175781,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002328306,"about_ca_topic_score_gemma":0.000001363248,"domain_scores_codex":[0.9977599,0.00004518022,0.001243201,0.0001971794,0.0004543212,0.0003002653],"domain_scores_gemma":[0.9969032,0.0009595396,0.00109598,0.0006626959,0.0002391831,0.000139362],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005502757,0.0002007903,0.000418189,0.0003347878,0.0002643323,0.0000302791,0.0002278814,0.00002122925,0.9938135,8.054037e-7,0.0001714097,0.003966505],"study_design_scores_gemma":[0.000382849,0.0000272144,0.0002055016,0.0003654188,0.0003010285,0.0004890703,0.0007484759,0.00001161166,0.9965101,0.0001543054,0.000601685,0.0002027195],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9881227,0.001481408,0.000004436829,0.0002143843,0.00003041194,0.00002543823,0.00006083455,0.00001900853,0.01004136],"genre_scores_gemma":[0.9953304,0.003377649,0.0001302811,0.00001940578,0.0001480905,0.00000149543,0.000005556609,0.00003269486,0.0009544227],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02453958,"threshold_uncertainty_score":0.9763398,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007874389293805274,"score_gpt":0.2032508544378366,"score_spread":0.1953764651440313,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}