{"id":"W2126827862","doi":"10.3390/molecules15053709","title":"Recent Advances in the Synthesis of Ammonium-Based Rotaxanes","year":2010,"lang":"en","type":"review","venue":"Molecules","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Centre québécois sur les matériaux fonctionnels","keywords":"Crown ether; Hydrogen bond; Ammonium; Chemistry; Solvent; Base (topology); Ammonium acetate; Nanotechnology; Combinatorial chemistry; Molecule; Materials science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004477361,0.0008229034,0.0007080228,0.0008480286,0.0002637983,0.0005069427,0.0005341758,0.0004900565,0.002565067],"category_scores_gemma":[0.0002802521,0.0003571264,0.0002762472,0.0008484995,0.000273367,0.0009897575,0.0005864366,0.0007154717,0.002683627],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004612982,"about_ca_system_score_gemma":0.0003913429,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003590103,"about_ca_topic_score_gemma":0.0005577458,"domain_scores_codex":[0.9998435,0.00002089112,0.00001918979,0.00004547961,0.000050066,0.00002083199],"domain_scores_gemma":[0.9998883,0.00003225584,0.00002711793,0.00000893426,0.00002685148,0.00001652739],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001575959,0.0001694387,0.0002424648,0.02138557,0.00007853121,0.0005230204,0.0001779137,0.00208975,0.1431261,0.013957,0.006810425,0.8112822],"study_design_scores_gemma":[0.00002967699,0.0002792836,0.0006577022,0.000648118,0.0000721827,0.00149988,0.0000576789,0.0007434201,0.07473064,0.003045744,0.9181875,0.00004806864],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.00526498,0.9804806,0.004513195,0.0002539145,0.0002942542,0.0000251477,0.00005560765,0.00007056756,0.009041856],"genre_scores_gemma":[0.02241892,0.9659954,0.006209281,0.0002147403,0.0002912325,0.0000409085,0.0001060186,0.00001730011,0.00470628],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.002565067,"threshold_uncertainty_score":0.008580983,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02445423716719016,"score_gpt":0.2914147592526086,"score_spread":0.2669605220854184,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}