{"id":"W2127186463","doi":"10.1002/anie.201310939","title":"Modification of Fluorescent Photoinduced Electron Transfer (PET) Sensors/Switches To Produce Molecular Photo‐Ionic Triode Action","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Engineering and Physical Sciences Research Council; Queen's University; Queen's University Belfast","keywords":"Photoinduced electron transfer; Triode; Fluorescence; Materials science; Electron transfer; Optoelectronics; Fluorophore; Photochemistry; Chemistry; Optics; Physics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002165123,0.0002421844,0.0002228831,0.0001855037,0.000080794,0.00004844739,0.000224483,0.0001423366,0.0006068716],"category_scores_gemma":[0.0002203728,0.0002591684,0.0001813072,0.0002025177,0.00003398821,0.0002002706,0.00002413868,0.0002418496,0.0000369359],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000283466,"about_ca_system_score_gemma":0.00004192155,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001096713,"about_ca_topic_score_gemma":0.00001518996,"domain_scores_codex":[0.99813,0.00002464603,0.0004526609,0.0005132953,0.000630887,0.0002484766],"domain_scores_gemma":[0.9989265,0.00005173587,0.0001536029,0.0003665732,0.000388761,0.0001128451],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003097186,0.0001599249,0.00001898595,0.00006892146,0.00008362391,0.00000223391,0.00009661802,0.0006670016,0.9947053,0.000123666,0.0005785546,0.003185492],"study_design_scores_gemma":[0.0008482065,0.00007487798,0.0001635591,0.00009049776,0.00005754534,0.00002955558,0.00005695438,0.002738067,0.9883805,0.0001356319,0.007171187,0.0002534024],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9654893,0.00004040629,0.03017822,0.000625427,0.0005911166,0.0002276757,0.00003689008,0.0001116042,0.002699335],"genre_scores_gemma":[0.9977451,0.00009665864,0.000236328,0.0001339274,0.0008106647,0.0001198923,0.0004030548,0.00004301762,0.000411351],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03225578,"threshold_uncertainty_score":0.9999861,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01679850218813761,"score_gpt":0.2615128187146365,"score_spread":0.2447143165264989,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}