{"id":"W2128380610","doi":"10.1039/c1dt10448a","title":"Intermolecular hydroamination of oxygen-substituted allenes. New routes for the synthesis of N,O-chelated zirconium and titanium amido complexes","year":2011,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hydroamination; Chemistry; Ligand (biochemistry); Trigonal bipyramidal molecular geometry; Heteroatom; Chelation; Steric effects; Allene; Medicinal chemistry; Zirconium; Metal; Polymer chemistry; Intramolecular force; Stereochemistry; Photochemistry; Catalysis; Organic chemistry; Molecule; Ring (chemistry)","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001870907,0.000389154,0.0001765139,0.0001621124,0.0001304022,0.0002585351,0.0004556617,0.00021513,0.001015602],"category_scores_gemma":[0.0001658035,0.0002331508,0.0002540847,0.0000989522,0.000194621,0.0003303309,0.0004211258,0.0004553491,0.0004674358],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002593882,"about_ca_system_score_gemma":0.0001660798,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003408996,"about_ca_topic_score_gemma":0.001465866,"domain_scores_codex":[0.9998858,0.00001546271,0.00001185322,0.00002449956,0.00003006487,0.00003235638],"domain_scores_gemma":[0.9999318,0.00000862784,0.00002408502,0.00001391635,0.000009741341,0.00001174733],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008255992,0.00003391876,0.0002021718,0.0002316678,0.0000293864,0.0003307333,0.0001863516,0.0003001918,0.9877108,0.003135176,0.0001630912,0.007593868],"study_design_scores_gemma":[0.00003120834,0.00028152,0.0005435665,0.00001032929,0.00002627039,0.0003893069,0.0000371097,0.0005864985,0.9880476,0.0002098185,0.009825294,0.00001138373],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9522623,0.004658903,0.0264831,0.0001794159,0.00009979145,0.0001282057,0.0002363009,0.0002250719,0.015727],"genre_scores_gemma":[0.9839759,0.002300525,0.009564414,0.00005223235,0.00001466756,0.0000421548,0.0001734047,0.00002542401,0.003851284],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001015602,"threshold_uncertainty_score":0.003397524,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02572739819590188,"score_gpt":0.2324603505860962,"score_spread":0.2067329523901943,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}