{"id":"W2128770585","doi":"10.1002/anie.200700975","title":"Catalytic Enantioselective Preparation of α‐Substituted Allylboronates: One‐Pot Addition to Functionalized Aldehydes and a Route to Chiral Allylic Trifluoroborate Reagents","year":2007,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":165,"is_retracted":false,"has_abstract":true,"ca_institutions":"Alberta Glycomics Centre; University of Alberta","funders":"","keywords":"Enantioselective synthesis; Reagent; Allylic rearrangement; Tsuji–Trost reaction; Chemistry; Catalysis; Combinatorial chemistry; Alkylation; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004040271,0.0002397722,0.0002975237,0.0003925423,0.0001036673,0.00005894822,0.0002103116,0.0001591427,0.0006651867],"category_scores_gemma":[0.0008029651,0.000253719,0.0001201159,0.0005488679,0.00005310747,0.0004322607,0.0000731261,0.0001199621,0.00004111368],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003816801,"about_ca_system_score_gemma":0.00007209707,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002136883,"about_ca_topic_score_gemma":0.0001602595,"domain_scores_codex":[0.9979406,0.00001211371,0.0005803959,0.0005191573,0.0006819026,0.0002658518],"domain_scores_gemma":[0.9984359,0.0002419915,0.0003068045,0.0002215049,0.0006016199,0.0001922184],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001977492,0.0006102964,0.001095922,0.00009177732,0.0008696374,0.000010475,0.0009958579,0.0001368858,0.9445228,0.0007131744,0.007157549,0.04181814],"study_design_scores_gemma":[0.0007306288,0.00006609938,0.007706148,0.0001792268,0.0001277151,0.00001157157,0.0001690976,0.00007966457,0.9832807,0.00037605,0.007008239,0.0002648642],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8414128,0.0002866632,0.06521142,0.001506187,0.001108115,0.0008067937,0.00207043,0.0002854641,0.08731209],"genre_scores_gemma":[0.9927998,0.00005880626,0.00125652,0.000197675,0.0008310012,0.0001179312,0.003296826,0.00002763143,0.001413845],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1513869,"threshold_uncertainty_score":0.9999915,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01745949003782568,"score_gpt":0.2782348305428844,"score_spread":0.2607753405050588,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}