{"id":"W2128863896","doi":"10.1139/v07-121","title":"Molecular studies of the initiation and termination steps of the anionic polymerization of P=C bonds","year":2007,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Carbanion; Steric effects; Reactivity (psychology); Polymerization; Stereochemistry; Medicinal chemistry; Solid-state; Electrophile; Crystallography; Catalysis; Organic chemistry; Polymer","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002210692,0.0003507327,0.0001721536,0.00009133961,0.0001816358,0.0001783274,0.0003491555,0.0003102953,0.001253767],"category_scores_gemma":[0.0003214071,0.0001658578,0.0001837012,0.000116802,0.0002125604,0.0003402642,0.0001099811,0.0009850458,0.0001985837],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003557344,"about_ca_system_score_gemma":0.0001687409,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005124803,"about_ca_topic_score_gemma":0.0003175969,"domain_scores_codex":[0.9999356,0.000009618839,0.000002566246,0.00001181553,0.00002260814,0.00001764708],"domain_scores_gemma":[0.9998835,0.00004003061,0.00003737381,0.000008514397,0.00001316342,0.00001736334],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000189666,0.0001792378,0.0003437845,0.0001679229,0.00001444138,0.0001569236,0.00007225706,0.003979484,0.9900456,0.0022428,0.0000893492,0.002518558],"study_design_scores_gemma":[0.00004577802,0.0007841691,0.001117497,0.000009889018,0.00001716407,0.0000814433,0.0000229588,0.01012048,0.9860923,0.0001683922,0.001526692,0.00001337673],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9945635,0.0005000524,0.002482117,0.00004191972,0.000008709812,0.00003991099,0.00009120205,0.00004009464,0.002232538],"genre_scores_gemma":[0.9955753,0.0006955111,0.002470362,0.00001030736,0.000006536327,0.00003385639,0.0001151054,0.000007775179,0.001085218],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001253767,"threshold_uncertainty_score":0.0041942,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01253023122947157,"score_gpt":0.2247073617441144,"score_spread":0.2121771305146428,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}