{"id":"W2129550441","doi":"10.1039/c3cp44295k","title":"Ultrafast photoinduced dynamics of halogenated cyclopentadienes: observation of geminate charge-transfer complexes in solution","year":2013,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Chemistry; Photochemistry; Homolysis; Radical; Dissociation (chemistry); Solvent; Halogen; Photodissociation; Femtosecond; Molecule; Solvent effects; Spectroscopy; Physical chemistry; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00005685753,0.0004590092,0.0008351006,0.00001637649,0.00005039256,0.00001386801,0.0004843037,0.0002260093,0.0002268143],"category_scores_gemma":[0.0000471442,0.0004788447,0.0003022252,0.0004285504,0.0004879919,0.0002380869,0.00007361237,0.0005280016,0.000009215751],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002120932,"about_ca_system_score_gemma":0.00005323085,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002516151,"about_ca_topic_score_gemma":0.000003727636,"domain_scores_codex":[0.9977117,0.00001117855,0.00071553,0.0005592582,0.0004071769,0.0005951624],"domain_scores_gemma":[0.998828,0.0001543127,0.0001603888,0.0004531061,0.0002670664,0.0001371029],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009852411,0.001207745,0.0008266745,0.001498359,0.0001076243,0.000001177927,0.0004266045,0.00003044767,0.9951928,0.0002127805,0.0000181605,0.0003791559],"study_design_scores_gemma":[0.001049913,0.00001751547,0.0001741008,0.0002051095,0.00006100625,0.000002336533,0.0001643248,0.007705398,0.9870239,0.00316128,0.000006062837,0.0004290488],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940476,0.00002632147,0.0001464581,0.00007664043,0.00001334581,0.0001930949,0.0001887125,0.00006849563,0.005239274],"genre_scores_gemma":[0.9986577,0.00002822614,0.0000399457,0.00001454919,0.0001424779,0.0001494355,0.0007964504,0.00004485377,0.0001263494],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008168843,"threshold_uncertainty_score":0.9997663,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01583080710310452,"score_gpt":0.2303037630621199,"score_spread":0.2144729559590154,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}