{"id":"W2129704694","doi":"10.1021/nn100023h","title":"Nanoscale Shape and Size Control of Cubic, Cuboctahedral, and Octahedral Cu−Cu<sub>2</sub>O Core−Shell Nanoparticles on Si(100) by One-Step, Templateless, Capping-Agent-Free Electrodeposition","year":2010,"lang":"en","type":"article","venue":"ACS Nano","topic":"Copper-based nanomaterials and applications","field":"Materials Science","cited_by":208,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Materials science; Nanoparticle; X-ray photoelectron spectroscopy; Cubic crystal system; Octahedron; Nanoscopic scale; Nanotechnology; Metal; Chemical engineering; Shell (structure); Copper; Crystallography; Crystal structure; Chemistry; Metallurgy; Composite material","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004294822,0.0003706352,0.0005691621,0.00007323931,0.0003896559,0.0002012341,0.0004212321,0.0002394581,0.0001369234],"category_scores_gemma":[0.000179684,0.0003482195,0.00007087394,0.0002253596,0.00040464,0.0003008905,0.0001631895,0.0001746614,0.00006592998],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003742537,"about_ca_system_score_gemma":0.00008156879,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002299342,"about_ca_topic_score_gemma":0.0001939711,"domain_scores_codex":[0.9975282,0.0001009452,0.0006548471,0.0007195519,0.0003866771,0.0006097681],"domain_scores_gemma":[0.9981744,0.0003450447,0.0003482113,0.0007366549,0.0001578642,0.0002377913],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002573845,0.0003241008,0.0006922499,0.00006690755,0.00001943298,0.000003927992,0.00007866049,0.000002310654,0.994115,0.001086679,0.002160145,0.001193229],"study_design_scores_gemma":[0.002095568,0.0004792669,0.002279915,0.0000657334,0.00008445024,0.00003386638,0.00002390803,0.0003445059,0.992775,0.0005462642,0.0008819994,0.0003895733],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969481,0.0003503063,0.00004778034,0.0008938325,0.0002975379,0.0007613056,0.0004967214,0.0001327609,0.00007164377],"genre_scores_gemma":[0.9985736,0.0001945372,0.0004390694,0.0003849415,0.0001332819,0.0001363481,0.00003931038,0.00005019895,0.00004873323],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001838183,"threshold_uncertainty_score":0.999897,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01019444983092585,"score_gpt":0.2247652289680035,"score_spread":0.2145707791370776,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}