{"id":"W2129821016","doi":"10.1021/ja407004y","title":"Synthesis, Electronic Structure, and Magnetism of [Ni(6-Mes)<sub>2</sub>]<sup>+</sup>: A Two-Coordinate Nickel(I) Complex Stabilized by Bulky N-Heterocyclic Carbenes","year":2013,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":265,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Engineering and Physical Sciences Research Council","keywords":"Chemistry; Nickel; Magnetism; Carbene; Cationic polymerization; Crystallography; Atomic orbital; Density functional theory; Anisotropy; Magnetic anisotropy; Computational chemistry; Condensed matter physics; Magnetization; Physics; Polymer chemistry; Magnetic field; Electron; Quantum mechanics; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004830753,0.0001450469,0.0001374461,0.00008857119,0.0001760287,0.0002805173,0.0002971876,0.0001775478,0.0007007191],"category_scores_gemma":[0.0001459452,0.0001023343,0.0000398037,0.00009016545,0.0001688761,0.0001316289,0.0001255738,0.0001687232,0.0001087585],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002903147,"about_ca_system_score_gemma":0.0001300384,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008307671,"about_ca_topic_score_gemma":0.001872736,"domain_scores_codex":[0.9999533,0.000006116687,0.00000303817,0.00001168285,0.00001820845,0.00000766601],"domain_scores_gemma":[0.9999665,0.000004053816,0.000008860127,0.000004119552,0.000007693827,0.000008725618],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002159568,0.0000298504,0.0002751581,0.00006082714,0.000006162023,0.00005535686,0.00004955622,0.000594562,0.9952177,0.0009262877,0.0001155334,0.002453089],"study_design_scores_gemma":[0.00003543661,0.0002012158,0.001756347,0.000003545045,0.000007650779,0.0001147849,0.00003749708,0.002179805,0.9927911,0.0001014212,0.002762055,0.000009244103],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977703,0.0001829934,0.0004548421,0.00003035899,0.000003620519,0.000006903088,0.00006213335,0.00001663835,0.001472303],"genre_scores_gemma":[0.9978743,0.0001057204,0.0009670463,0.000009732084,0.000002323668,0.000007593029,0.0001340222,0.00000874943,0.0008905442],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008307671,"threshold_uncertainty_score":0.002344131,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006916047418450472,"score_gpt":0.2279473468947898,"score_spread":0.2210312994763393,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}