{"id":"W2129825728","doi":"10.1021/jo016061c","title":"Asymmetric Methoxyselenenylations and Cyclizations with 3-Camphorseleno Electrophiles Containing Oxime Substituents at C-2. Formation of an Unusual Oxaselenazole from an Oxime-Substituted Selenenyl Bromide","year":2002,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Organoselenium and organotellurium chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Electrophile; Oxime; Bromide; Medicinal chemistry; Diselenide; Trifluoromethanesulfonate; Electrophilic addition; Stereochemistry; Organic chemistry; Catalysis; Selenium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001877519,0.0006272873,0.0002209861,0.0002004316,0.0001396056,0.0002308408,0.0002121213,0.000271135,0.001209741],"category_scores_gemma":[0.0002036276,0.0001864507,0.0003044821,0.0002049291,0.0002000215,0.000322597,0.0003486187,0.0004988772,0.0006379332],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002006117,"about_ca_system_score_gemma":0.0002581021,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003060939,"about_ca_topic_score_gemma":0.001014012,"domain_scores_codex":[0.9998536,0.00003001515,0.00001570447,0.00002298321,0.0000286347,0.00004902692],"domain_scores_gemma":[0.999899,0.00001193744,0.0000328334,0.0000176686,0.00001399801,0.00002460476],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008538842,0.00002709497,0.0001221856,0.00003720254,0.00001094746,0.0001793157,0.00005775064,0.0001169238,0.9955074,0.0003096334,0.00003527285,0.003510998],"study_design_scores_gemma":[0.000008303791,0.0001961293,0.0005376472,0.000002523988,0.000009670895,0.0001731406,0.00001933453,0.0001513817,0.9973361,0.00003317784,0.001527988,0.000004534784],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9852183,0.001227905,0.007208986,0.0000985563,0.00005486442,0.00008088254,0.0002265787,0.0001261746,0.005757743],"genre_scores_gemma":[0.9898728,0.001106273,0.004283752,0.00004575316,0.00001527036,0.0000429209,0.0003877889,0.00003020697,0.004215288],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001209741,"threshold_uncertainty_score":0.004046977,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04516787688290847,"score_gpt":0.3266446342399601,"score_spread":0.2814767573570516,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}