{"id":"W2129825728","doi":"10.1021/jo016061c","title":"Asymmetric Methoxyselenenylations and Cyclizations with 3-Camphorseleno Electrophiles Containing Oxime Substituents at C-2. Formation of an Unusual Oxaselenazole from an Oxime-Substituted Selenenyl Bromide","year":2002,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Organoselenium and organotellurium chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Electrophile; Oxime; Bromide; Medicinal chemistry; Diselenide; Trifluoromethanesulfonate; Electrophilic addition; Stereochemistry; Organic chemistry; Catalysis; Selenium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006672952,0.0003611821,0.0005084247,0.0001183406,0.0004850553,0.00003611871,0.000540565,0.0004013527,0.002438213],"category_scores_gemma":[0.0002193336,0.0002852332,0.00007958255,0.0007343179,0.0003018367,0.0005942033,0.00008541947,0.000900463,0.00002022409],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002256161,"about_ca_system_score_gemma":0.0001404033,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001678804,"about_ca_topic_score_gemma":0.0000222459,"domain_scores_codex":[0.9976863,0.0003263516,0.0008942926,0.0002665413,0.0004069585,0.0004195285],"domain_scores_gemma":[0.9972513,0.0005342569,0.001025556,0.0003707107,0.0004177901,0.0004004271],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005486424,0.0004616701,0.002701697,0.00006430861,0.0002728453,0.00001993442,0.001239656,0.000382606,0.9933478,0.000005825948,0.0001682452,0.0007868192],"study_design_scores_gemma":[0.002822959,0.0002201977,0.00179925,0.00003995828,0.0008961649,0.0008988892,0.0004761824,0.003091497,0.9887466,0.00007508185,0.0006142211,0.0003189954],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954814,0.002336354,0.001244974,0.0002182866,0.0001026753,0.0001599007,0.00009603852,0.00005315111,0.0003072438],"genre_scores_gemma":[0.9967586,0.001423511,0.001033065,0.0001269393,0.0003536729,0.000002839343,0.0001126964,0.00005697759,0.0001316872],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004601146,"threshold_uncertainty_score":0.99996,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04516787688290847,"score_gpt":0.3266446342399601,"score_spread":0.2814767573570516,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}