{"id":"W2130339795","doi":"10.1002/chin.200626036","title":"Heck, Direct Arylation, and Hydrogenation: Two or Three Sequential Reactions from a Single Catalyst.","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Catalysis; Combinatorial chemistry; Heck reaction; Organic chemistry; Palladium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006689029,0.0002027853,0.0001967032,0.00005937733,0.0002509751,0.0001591055,0.000120719,0.0001323864,0.001186444],"category_scores_gemma":[0.0001150039,0.0001985691,0.00008827534,0.0002009175,0.0001385111,0.0003497957,0.00007016415,0.0001688213,0.00007853041],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002945483,"about_ca_system_score_gemma":0.00009668334,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004267823,"about_ca_topic_score_gemma":0.003028228,"domain_scores_codex":[0.9987965,3.072864e-8,0.000405771,0.0003174927,0.0002385717,0.0002416785],"domain_scores_gemma":[0.9990128,0.000159805,0.0001864396,0.0004462918,0.000104527,0.00009010197],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006215594,0.0001557806,0.001478652,0.00006548548,0.0001039428,0.00001669932,0.0002348457,0.00004395809,0.9801241,0.0001319159,0.004441606,0.01314089],"study_design_scores_gemma":[0.0007515841,0.000005573451,0.000426913,0.00004324798,0.00009470156,0.00009274789,0.00009089578,0.001027115,0.9663969,0.0005989815,0.03020117,0.0002701471],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.79835,0.000127185,0.00001646666,0.0001135164,0.0001329988,0.00008192638,0.0001822424,0.0002840867,0.2007115],"genre_scores_gemma":[0.9796427,0.000006445626,0.00006622219,0.00001616095,0.0006528807,0.00003525209,0.001679031,0.0000314221,0.01786983],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1828417,"threshold_uncertainty_score":0.9997266,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02011097304089309,"score_gpt":0.2575463324207112,"score_spread":0.2374353593798181,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}