{"id":"W2130443313","doi":"10.1002/adsc.200600268","title":"Design of a Conformationally Rigid Hydrazide Organic Catalyst","year":2007,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":69,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; University of Ottawa","keywords":"Chemistry; Hydrazide; Iminium; Organocatalysis; Catalysis; Combinatorial chemistry; Organic chemistry; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001238801,0.0004780426,0.0009813141,0.000629546,0.0002210397,0.0000390864,0.0008744697,0.0002435311,0.001764136],"category_scores_gemma":[0.001849326,0.0004580941,0.000487005,0.001717892,0.0002007552,0.0005072216,0.0001358081,0.0002059604,0.000282938],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002484998,"about_ca_system_score_gemma":0.0001435524,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001272696,"about_ca_topic_score_gemma":0.00004745074,"domain_scores_codex":[0.9963064,0.00004332952,0.001373796,0.000646836,0.0009324081,0.0006972675],"domain_scores_gemma":[0.9943189,0.002852253,0.0008864168,0.001343699,0.0003410427,0.0002576905],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00023134,0.0002905504,0.0006582985,0.0001691973,0.001170164,0.00002779325,0.000453683,0.0008830164,0.5051173,0.0001854895,0.00009756087,0.4907156],"study_design_scores_gemma":[0.0003364657,0.00001582084,0.0002685578,0.00008537724,0.0008009422,0.00002341694,0.0009148401,0.0006600072,0.9939743,0.0001870777,0.002199144,0.000534057],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.2642931,0.002869255,0.5995262,0.0002477516,0.0001971903,0.0005327361,0.0002521104,0.0006528725,0.1314288],"genre_scores_gemma":[0.9870872,0.0001909753,0.01146268,0.00005659095,0.00008426279,0.00004688682,0.0001838124,0.00007866762,0.0008089218],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.7227941,"threshold_uncertainty_score":0.9997871,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009315771662372883,"score_gpt":0.2273495786177187,"score_spread":0.2180338069553458,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}