{"id":"W2130539493","doi":"10.1039/c2cc32492j","title":"Unexpected evolution of optical properties in Ir–Pt complexes upon repeat unit increase: towards an understanding of the photophysical behaviour of organometallic polymers","year":2012,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Polymer; Chemistry; Iridium; Photochemistry; Group 2 organometallic chemistry; Energy transfer; Polymer chemistry; Crystallography; Molecule; Catalysis; Organic chemistry; Chemical physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001491675,0.0002465843,0.0002255206,0.0001046324,0.000127429,0.0005554926,0.0004041084,0.0004685074,0.001581042],"category_scores_gemma":[0.0004792769,0.0002539389,0.0001510455,0.0001293539,0.0003141947,0.0005273703,0.0001689536,0.0007264571,0.0002908999],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002726933,"about_ca_system_score_gemma":0.00007720859,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001531059,"about_ca_topic_score_gemma":0.0001418573,"domain_scores_codex":[0.9998949,0.00001446512,0.000008015945,0.00003121943,0.000028911,0.00002246404],"domain_scores_gemma":[0.9998628,0.00003872182,0.0000371294,0.00002497514,0.00001376365,0.00002264292],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001039346,0.00001722649,0.0001317687,0.00003432857,0.00000659582,0.00004567809,0.00004468276,0.000200369,0.9977489,0.0001577758,0.00003878734,0.001469909],"study_design_scores_gemma":[0.000009675544,0.0001090771,0.001046973,0.000001792867,0.00000844291,0.0001078979,0.00001348618,0.001255263,0.9969671,0.00004407796,0.0004310046,0.00000530842],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996822,0.0003659485,0.001544979,0.00005130142,0.000007011293,0.00001003597,0.00005592623,0.0001093087,0.001033496],"genre_scores_gemma":[0.9984239,0.0001040845,0.0008470693,0.00002294168,0.000002935272,0.000008365928,0.00005143215,0.00002756236,0.0005116953],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001581042,"threshold_uncertainty_score":0.005289137,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07271662329841813,"score_gpt":0.2847769906422723,"score_spread":0.2120603673438542,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}