{"id":"W2131172140","doi":"10.1002/anie.201502579","title":"Catalytic Ketone Hydrodeoxygenation Mediated by Highly Electrophilic Phosphonium Cations","year":2015,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":113,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Electrophile; Phosphonium; Deoxygenation; Catalysis; Chemistry; Ketone; Hydrodeoxygenation; Alkane; Organic chemistry; Silane; Selectivity","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002267655,0.0002428614,0.0001997158,0.0002379674,0.0001066891,0.00008861881,0.000398444,0.0002065703,0.0009140607],"category_scores_gemma":[0.0006054604,0.0002611529,0.0001238527,0.0005932957,0.00007333268,0.0005097332,0.00006034903,0.0002411796,0.0004804703],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008607114,"about_ca_system_score_gemma":0.0001657352,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002191179,"about_ca_topic_score_gemma":0.0000231905,"domain_scores_codex":[0.9978276,0.00001334372,0.0004504189,0.0004462871,0.0009738142,0.0002884688],"domain_scores_gemma":[0.9984222,0.00009708882,0.0002741501,0.0003030697,0.0006384093,0.0002650583],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009270616,0.0005610071,0.0004131664,0.00002857548,0.0004022458,0.00001352881,0.0005264338,0.0000916581,0.6140983,0.0006478873,0.3804799,0.002644637],"study_design_scores_gemma":[0.0009287702,0.0000158374,0.00003443044,0.00001361342,0.00005438132,0.00001972394,0.0001430354,0.001365833,0.884349,0.0004567885,0.1123589,0.0002596933],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3521908,0.003306837,0.0245356,0.02461595,0.004719725,0.0005932932,0.003475452,0.001921681,0.5846407],"genre_scores_gemma":[0.9684226,0.0001522797,0.00007529891,0.000424919,0.0009455538,0.0001152612,0.02293246,0.0000390923,0.006892544],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6162318,"threshold_uncertainty_score":0.9999992,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01236234316718155,"score_gpt":0.2386963669891409,"score_spread":0.2263340238219594,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}