{"id":"W2131172140","doi":"10.1002/anie.201502579","title":"Catalytic Ketone Hydrodeoxygenation Mediated by Highly Electrophilic Phosphonium Cations","year":2015,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":113,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Electrophile; Phosphonium; Deoxygenation; Catalysis; Chemistry; Ketone; Hydrodeoxygenation; Alkane; Organic chemistry; Silane; Selectivity","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00013783,0.0004826763,0.0001947184,0.0001289432,0.00008041332,0.0001906662,0.0002572783,0.0001888969,0.001184898],"category_scores_gemma":[0.0001480736,0.0001286402,0.0001309821,0.0001335757,0.0002032653,0.0003033601,0.0002557373,0.0003068925,0.0003083125],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001495489,"about_ca_system_score_gemma":0.0001099172,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002299426,"about_ca_topic_score_gemma":0.0005133056,"domain_scores_codex":[0.9999063,0.000012592,0.000006881399,0.0000197709,0.00001529564,0.00003915457],"domain_scores_gemma":[0.9999282,0.00001388821,0.0000240542,0.00001062396,0.000008738673,0.00001441261],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002018577,0.00001600725,0.0001616216,0.0001147379,0.000008896115,0.0001216422,0.00004688655,0.0001940371,0.9949758,0.0003475062,0.00008654049,0.003724429],"study_design_scores_gemma":[0.000007543553,0.0000959801,0.0003432643,0.000002997392,0.000004650339,0.00006101541,0.00001002922,0.0002207053,0.9982828,0.00002436952,0.000942848,0.000003823248],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9941876,0.001076557,0.001790711,0.00003586417,0.00004100773,0.00001322879,0.0001564324,0.00006072583,0.00263798],"genre_scores_gemma":[0.9979876,0.0005526094,0.0005524587,0.00001006088,0.000003213282,0.000005773069,0.00008917884,0.00001044739,0.0007885905],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001184898,"threshold_uncertainty_score":0.003963947,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01236234316718155,"score_gpt":0.2386963669891409,"score_spread":0.2263340238219594,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}