{"id":"W2131300886","doi":"10.1039/c5cc06779k","title":"Are the orientation and bond strength of the RCO<sub>2</sub><sup>−</sup>⋯M link key factors for ultrafast electron transfers?","year":2015,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal; Université de Sherbrooke","funders":"","keywords":"Electron; Link (geometry); Orientation (vector space); Ultrashort pulse; Key (lock); Bond strength; Materials science; Atomic physics; Chemistry; Physics; Crystallography; Nanotechnology; Nuclear physics; Computer science; Mathematics; Optics; Geometry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001340532,0.0001990768,0.000222834,0.00001329596,0.0003425513,0.00002863243,0.0008813778,0.0001376948,0.000002978549],"category_scores_gemma":[0.0003222424,0.0001364804,0.0001382643,0.0001818193,0.0004984173,0.00007371527,0.00009816909,0.0004666165,6.235477e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007269716,"about_ca_system_score_gemma":0.00007298962,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001172836,"about_ca_topic_score_gemma":0.00002429586,"domain_scores_codex":[0.9989741,0.0000333452,0.0003116237,0.0002222287,0.0001863866,0.0002723107],"domain_scores_gemma":[0.9979476,0.0005894633,0.0001130138,0.001085004,0.0001713143,0.00009356322],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006782737,0.0001261386,0.001440704,0.00009457461,0.0001023453,3.905589e-8,0.003562091,0.000006541225,0.993333,0.0004542858,0.0003701482,0.0004422653],"study_design_scores_gemma":[0.0006256151,0.00002109681,0.0002137718,0.00004505446,0.0001231883,0.000002773502,0.003895047,0.0001589658,0.9923347,0.0007718308,0.001656473,0.0001515448],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9951771,0.0006203561,0.00006113674,0.002356288,0.0000114138,0.0002354063,0.0002048516,0.00004413103,0.001289355],"genre_scores_gemma":[0.999129,0.0002848041,0.00006144429,0.00006093689,0.00004871597,0.0001865332,0.000178797,0.00002079369,0.00002899291],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003951921,"threshold_uncertainty_score":0.5565507,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.031029500461572,"score_gpt":0.264416616662181,"score_spread":0.233387116200609,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}