{"id":"W2131701421","doi":"10.1021/om800780f","title":"Palladium-Catalyzed Intramolecular Coupling of Arenes and Unactivated Alkanes in Air","year":2008,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":133,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Amgen","keywords":"Chemistry; Palladium; Regioselectivity; Alkane; Catalysis; Intramolecular force; Substituent; Azole; Ring (chemistry); Alkene; Medicinal chemistry; Organic chemistry; Photochemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002324354,0.0006987479,0.0002909756,0.0003192072,0.0002777604,0.0003041351,0.0005255303,0.0002511722,0.002071963],"category_scores_gemma":[0.0001370928,0.000289004,0.000221344,0.0002655681,0.0002277999,0.0004533676,0.0003433797,0.000744501,0.0007885063],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001872167,"about_ca_system_score_gemma":0.0002477211,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003698894,"about_ca_topic_score_gemma":0.0009688395,"domain_scores_codex":[0.9997975,0.0000193242,0.00001135098,0.00004664047,0.0000506041,0.00007455742],"domain_scores_gemma":[0.9999367,0.00001093278,0.00001529214,0.00001063126,0.00001133344,0.00001513789],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009462253,0.00007921956,0.00008582014,0.000159399,0.00001893252,0.0001508291,0.00008198447,0.0002472177,0.9917115,0.001209814,0.0001956203,0.005965068],"study_design_scores_gemma":[0.00001665615,0.0001451996,0.0002670158,0.000004565299,0.0000115774,0.0001033661,0.00001293401,0.0002720628,0.9949954,0.00006568531,0.004100056,0.000005520378],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9468799,0.003778896,0.02254757,0.0001291599,0.0002270407,0.0001292771,0.000301632,0.0004414485,0.02556518],"genre_scores_gemma":[0.9828479,0.002289205,0.005332746,0.00003992267,0.00002864593,0.00004947879,0.0002622682,0.0000516427,0.00909826],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002071963,"threshold_uncertainty_score":0.006931424,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02085697229690046,"score_gpt":0.2476998445202414,"score_spread":0.2268428722233409,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}