{"id":"W2132394148","doi":"10.1002/mrc.1052","title":"Use of <sup>19</sup>F NMR spectroscopy to probe enzymatic oxidation of fluorine‐tagged sulfides","year":2002,"lang":"en","type":"article","venue":"Magnetic Resonance in Chemistry","topic":"Peroxisome Proliferator-Activated Receptors","field":"Biochemistry, Genetics and Molecular Biology","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"Health Canada; Carleton University","funders":"Basic Energy Sciences; Natural Sciences and Engineering Research Council of Canada; U.S. Department of Energy","keywords":"Chemistry; Chemoselectivity; Substituent; Substrate (aquarium); Enzyme; Nuclear magnetic resonance spectroscopy; Fluorine-19 NMR; Fatty acid; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000149732,0.0002581515,0.0003434259,0.0000647337,0.00002773452,0.00002041658,0.0003206464,0.0002430374,0.0003939391],"category_scores_gemma":[0.0006014667,0.0002691605,0.00008568104,0.0003663224,0.0001394023,0.00001307051,0.0001261637,0.0001627937,0.000009745734],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005516889,"about_ca_system_score_gemma":0.00006092396,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004231104,"about_ca_topic_score_gemma":0.000005324383,"domain_scores_codex":[0.9982268,0.00004647258,0.0005932966,0.0004892575,0.000287082,0.0003571429],"domain_scores_gemma":[0.9989098,0.00003857239,0.0001762933,0.0006203832,0.0001283188,0.0001266484],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001105851,0.0001984239,0.01330312,0.0002311688,0.00001029634,0.000002773559,0.0001599112,0.0003606439,0.9820356,0.000003832394,0.001551367,0.002032316],"study_design_scores_gemma":[0.0005500222,0.0002281009,0.001121811,0.000135339,0.000009742659,0.000009874313,0.00006109539,0.0005019774,0.9890542,0.00002518058,0.008056936,0.0002457244],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960563,0.002923009,0.0001054883,0.0001059575,0.00002260304,0.0003438875,0.00002826534,0.0000148925,0.0003996402],"genre_scores_gemma":[0.9913369,0.0005967146,0.006336966,0.00006540481,0.00009807801,0.00008995084,0.00004216713,0.00003652955,0.001397251],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01218131,"threshold_uncertainty_score":0.999976,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01833725320229761,"score_gpt":0.2383126444903665,"score_spread":0.2199753912880689,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}