{"id":"W2132543205","doi":"10.5194/acp-11-4319-2011","title":"Size distribution of alkyl amines in continental particulate matter and their online detection in the gas and particle phase","year":2011,"lang":"en","type":"article","venue":"Atmospheric chemistry and physics","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":117,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Dimethylamine; Diethylamine; Aerosol; Trimethylamine; Chemistry; Particulates; Particle (ecology); Particle size; Analytical Chemistry (journal); Ethylamine; Alkyl; Ammonium; Detection limit; Environmental chemistry; Chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001821299,0.0002799172,0.0001260384,0.0006360542,0.0003214672,0.0002922974,0.0002981164,0.0003210549,0.001033536],"category_scores_gemma":[0.0002538583,0.0001450403,0.000136481,0.0003596814,0.0001735157,0.0001695748,0.0002495628,0.0002034029,0.0004337371],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001645058,"about_ca_system_score_gemma":0.0001268431,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004923548,"about_ca_topic_score_gemma":0.007973253,"domain_scores_codex":[0.9998234,0.00001639583,0.000008105124,0.00007969605,0.00005800119,0.00001437591],"domain_scores_gemma":[0.9998286,0.00003692277,0.0000334185,0.00001230317,0.00006841437,0.00002039302],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001441876,0.00002384958,0.03253266,0.00005570613,0.00003263443,0.00007999452,0.00009856127,0.0001063554,0.9589939,0.00003372123,0.00006903223,0.007829512],"study_design_scores_gemma":[0.0000118234,0.0005142599,0.5594239,0.00001486564,0.0000500808,0.0005591909,0.0001730848,0.00154523,0.4343298,0.00004884158,0.003308029,0.00002107732],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9869625,0.0008156195,0.007685331,0.00002322476,0.00001333066,0.00006193245,0.001278898,0.0001313968,0.003027778],"genre_scores_gemma":[0.9766723,0.0007725784,0.01813032,0.00009014136,0.00001723879,0.00008711058,0.001740038,0.0000403312,0.002449962],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004923548,"threshold_uncertainty_score":0.009789765,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01004486196254555,"score_gpt":0.2010217866295433,"score_spread":0.1909769246669978,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}