{"id":"W2132725563","doi":"10.1002/chin.200926068","title":"ChemInform Abstract: Selective C—H Activation α to Primary Amines. Bridging Metallaaziridines for Catalytic, Intramolecular α‐Alkylation.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Bridging (networking); Intramolecular force; Alkylation; Catalysis; Primary (astronomy); Combinatorial chemistry; Medicinal chemistry; Stereochemistry; Organic chemistry; Computer network","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001654881,0.0007932667,0.0002770289,0.0002898788,0.0002038775,0.0002093369,0.000582355,0.0003566725,0.0161133],"category_scores_gemma":[0.000143119,0.0002809573,0.0001782135,0.0002538697,0.0001723833,0.0004950978,0.0003162237,0.0005589754,0.006056816],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003789647,"about_ca_system_score_gemma":0.0002220396,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004525906,"about_ca_topic_score_gemma":0.0009292047,"domain_scores_codex":[0.9998865,0.000009997942,0.000005870608,0.00003284671,0.00003526035,0.00002945742],"domain_scores_gemma":[0.9999676,0.000005671531,0.000009368689,0.000004596784,0.000004775921,0.000007930692],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005005129,0.00007438737,0.0001216048,0.001033757,0.0000332411,0.0003185893,0.00008708599,0.0003903739,0.9102545,0.003468443,0.02501948,0.05869797],"study_design_scores_gemma":[0.00009340348,0.0004443304,0.0006860268,0.00003633913,0.00002722443,0.0004426378,0.00002076095,0.0009717164,0.9351339,0.0005307306,0.06159174,0.00002116172],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4753557,0.054484,0.1175001,0.002802425,0.003245026,0.0006537536,0.00909727,0.009636275,0.3272255],"genre_scores_gemma":[0.883101,0.01621713,0.01323557,0.0004990288,0.0003454816,0.0001480613,0.0030603,0.0003299512,0.08306344],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0161133,"threshold_uncertainty_score":0.05390441,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01297048074665168,"score_gpt":0.2425139103036542,"score_spread":0.2295434295570025,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}