{"id":"W2133331803","doi":"10.1002/chem.201103228","title":"Twisted Amide Analogues of Tröger’s Base","year":2012,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Molecular spectroscopy and chirality","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Amide; Protonation; Hydrolysis; Chemistry; Base (topology); Twist; Stereochemistry; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006449182,0.000226554,0.000257357,0.00002165844,0.0001233879,0.0000490684,0.0004233129,0.00005539121,0.004499263],"category_scores_gemma":[0.0001591866,0.0002110998,0.0002526023,0.0001019021,0.0001305941,0.000127355,0.00009130254,0.0006036065,0.00005450597],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006682971,"about_ca_system_score_gemma":0.00004748033,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002075906,"about_ca_topic_score_gemma":1.352348e-7,"domain_scores_codex":[0.9983997,0.0001019088,0.000543953,0.0001863857,0.0003028185,0.0004651935],"domain_scores_gemma":[0.9986198,0.00002494377,0.0003967122,0.0004523525,0.0000856846,0.0004204957],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004837602,0.0001845111,0.003829302,0.0001727661,0.00007450893,0.0001479297,0.0002497211,0.00000375023,0.992835,0.00001588533,0.00150957,0.0009286748],"study_design_scores_gemma":[0.000679015,0.00001434074,0.001723126,0.0001137005,0.00006822,0.0006906011,0.000176692,0.00004643335,0.9808661,0.00002715987,0.01534713,0.0002474377],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8705824,0.000753453,0.0003832107,0.00005582289,0.00007683472,0.00001368003,0.00002340102,0.00004703858,0.1280642],"genre_scores_gemma":[0.9960627,0.00005498501,0.0006888368,0.00007027715,0.0009387642,7.761656e-7,0.0000356505,0.00004534747,0.002102666],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1259615,"threshold_uncertainty_score":0.9964108,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0195043078308031,"score_gpt":0.2399089849928577,"score_spread":0.2204046771620546,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}