{"id":"W2133437970","doi":"10.1002/rcm.589","title":"Study of the neurotransmitter dopamine and the neurotoxin 6‐hydroxydopamine by electrospray ionization coupled with tandem mass spectrometry","year":2002,"lang":"en","type":"article","venue":"Rapid Communications in Mass Spectrometry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of the Environment, Conservation and Parks; Queen's University; Trent University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Hydroxydopamine; Tandem mass spectrometry; Electrospray ionization; Protonation; Fragmentation (computing); Deprotonation; Mass spectrometry; Neurotoxin; Dopamine; Molecule; Dissociation (chemistry); Chromatography; Ion; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002794472,0.0003239377,0.000236248,0.0003967187,0.0002335363,0.0002908394,0.0002583207,0.000453209,0.0005273434],"category_scores_gemma":[0.0003478649,0.0001348667,0.000188013,0.0002518597,0.0002362784,0.0004428863,0.0001976845,0.0003908529,0.0001908421],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002211373,"about_ca_system_score_gemma":0.0002162146,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004788472,"about_ca_topic_score_gemma":0.0005878284,"domain_scores_codex":[0.9998699,0.00001626518,0.000006794784,0.00002922396,0.00005924846,0.00001851249],"domain_scores_gemma":[0.9998093,0.00004342213,0.0000547101,0.000008881617,0.00004791165,0.00003581484],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007785975,0.00001223272,0.0007125443,0.00004088059,0.00001670644,0.0001212349,0.0000306583,0.00002904126,0.9960097,0.0001371504,0.00001718366,0.002794735],"study_design_scores_gemma":[0.0000196475,0.0006762549,0.01930139,0.00001481385,0.00003971471,0.001824804,0.0001086247,0.001289633,0.9724582,0.0002472127,0.004005296,0.00001445245],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9731528,0.01235435,0.0119561,0.00009508761,0.00005505117,0.00004655773,0.0002171818,0.00003684382,0.0020861],"genre_scores_gemma":[0.9803238,0.005940774,0.01083649,0.000107885,0.00003434306,0.00003892837,0.0003822451,0.000014036,0.002321567],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005273434,"threshold_uncertainty_score":0.001764178,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01380476441636947,"score_gpt":0.2394327102074304,"score_spread":0.2256279457910609,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}