{"id":"W2133536350","doi":"","title":"Absorption and luminescence spectroscopy of transition metal compounds: from coordination geometries to excited-state properties (1)","year":2008,"lang":"en","type":"article","venue":"","topic":"Inorganic and Organometallic Chemistry","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Luminescence; Excited state; Absorption spectroscopy; Chemistry; Absorption (acoustics); Rhenium; Spectroscopy; Platinum; Coordination complex; Vibronic spectroscopy; Spectral line; Photochemistry; Metal; Materials science; Atomic physics; Inorganic chemistry; Optoelectronics; Optics; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00004978594,0.0001528781,0.0002320997,0.00006788381,0.00008718643,0.00001828304,0.00009855505,0.00007105215,0.0009446035],"category_scores_gemma":[0.00003832966,0.0001375816,0.00004272293,0.0002379039,0.0001546147,0.0001750998,0.00003137685,0.00008545631,0.00001678223],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006095965,"about_ca_system_score_gemma":0.00003357009,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003411131,"about_ca_topic_score_gemma":0.00001293265,"domain_scores_codex":[0.999088,0.000005835531,0.0002752703,0.000258318,0.0002165727,0.0001559287],"domain_scores_gemma":[0.9995503,0.00002805295,0.00007751118,0.0001701423,0.0001028997,0.00007106941],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007310414,0.00006334564,0.001073336,0.00008531961,0.0000346049,0.000002782135,0.001225538,0.000004190167,0.9971638,0.00001235856,0.0001685099,0.00009313813],"study_design_scores_gemma":[0.000398519,0.00002563943,0.002086313,0.00003745781,0.00002693688,0.00002240756,0.000443952,0.0001728171,0.9962788,0.00007667106,0.0002603008,0.0001701884],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942799,0.0002430161,0.002593773,0.0002088071,0.00002761399,0.0000645528,0.00004516702,0.00007483915,0.002462399],"genre_scores_gemma":[0.996655,0.00007616465,0.0008087097,0.00005077938,0.00006381,0.000006403237,0.00008327455,0.00001607162,0.002239825],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002375129,"threshold_uncertainty_score":0.9999686,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01397598954991078,"score_gpt":0.1964460938188846,"score_spread":0.1824701042689738,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}