{"id":"W2134069348","doi":"10.1002/psc.1220","title":"Synthesis of disulfated peptides corresponding to the <i>N</i>‐terminus of chemokines receptors CXCR6 (CXCR6<sub>1–20</sub>) and DARC (DARC<sub>8–42</sub>) using a sulfate‐protecting group strategy","year":2010,"lang":"en","type":"article","venue":"Journal of Peptide Science","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Yükseköğretim Kurulu; Natural Sciences and Engineering Research Council of Canada; Council for Higher Education","keywords":"Chemistry; Hydrogenolysis; Protecting group; Stereochemistry; Peptide; Tyrosine; Sulfation; Receptor; Peptide synthesis; Indole test; Biochemistry; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001832946,0.0004770956,0.0002592566,0.0001253906,0.0001376159,0.0001578894,0.0002539863,0.0003332902,0.001276335],"category_scores_gemma":[0.0001483727,0.0001709194,0.0003061605,0.0001736968,0.0001138249,0.000280172,0.0002032108,0.0005120512,0.0005962521],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000143298,"about_ca_system_score_gemma":0.0002063235,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001100205,"about_ca_topic_score_gemma":0.0002225613,"domain_scores_codex":[0.999894,0.00001683576,0.0000110882,0.00001995771,0.00003033337,0.00002782304],"domain_scores_gemma":[0.9998889,0.00001461569,0.00003578511,0.000008493364,0.00002170603,0.0000304868],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004565984,0.00001848013,0.00004189136,0.00006507769,0.000004662646,0.0000501493,0.00001694523,0.0000956487,0.9978347,0.0001036095,0.00004582854,0.001677302],"study_design_scores_gemma":[0.0000153194,0.0003679612,0.0004434512,0.00000416525,0.00001045682,0.000154472,0.00001017304,0.0004405628,0.9956841,0.00003957465,0.002822154,0.000007684424],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9773396,0.001448711,0.01667278,0.000117521,0.0001122204,0.0001538873,0.0006852367,0.0001137882,0.003356285],"genre_scores_gemma":[0.9521444,0.002657189,0.0377863,0.0002230914,0.00004774923,0.0001612139,0.001707647,0.00006108268,0.005211333],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001276335,"threshold_uncertainty_score":0.004269779,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0107673809648173,"score_gpt":0.2519158000427404,"score_spread":0.2411484190779231,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}