{"id":"W2134069348","doi":"10.1002/psc.1220","title":"Synthesis of disulfated peptides corresponding to the <i>N</i>‐terminus of chemokines receptors CXCR6 (CXCR6<sub>1–20</sub>) and DARC (DARC<sub>8–42</sub>) using a sulfate‐protecting group strategy","year":2010,"lang":"en","type":"article","venue":"Journal of Peptide Science","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Yükseköğretim Kurulu; Natural Sciences and Engineering Research Council of Canada; Council for Higher Education","keywords":"Chemistry; Hydrogenolysis; Protecting group; Stereochemistry; Peptide; Tyrosine; Sulfation; Receptor; Peptide synthesis; Indole test; Biochemistry; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002720492,0.0002817688,0.0005396014,0.0003019689,0.0003411088,0.0001207528,0.0007993743,0.0001475336,0.00001226534],"category_scores_gemma":[0.002930836,0.0001997714,0.0002930617,0.0009851092,0.0008377428,0.000064308,0.0003141735,0.0003967323,9.348311e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004038842,"about_ca_system_score_gemma":0.0002224074,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005965462,"about_ca_topic_score_gemma":0.0001249387,"domain_scores_codex":[0.9973813,0.0001268504,0.0009021639,0.0004647198,0.0006615754,0.0004633885],"domain_scores_gemma":[0.9975131,0.0002409562,0.001039473,0.0004239308,0.0004999515,0.0002826051],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000146804,0.00006673473,0.001919682,0.00003993817,0.0000565127,0.000005915279,0.0001148435,0.0002340909,0.9819673,0.000006948845,0.00005550487,0.01538577],"study_design_scores_gemma":[0.0002121719,0.000200966,0.002672202,0.0002249503,0.0001152051,0.0001435861,0.0004859974,0.0004418336,0.9950697,0.00004664164,0.0001496874,0.0002370574],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9989272,0.0001506132,0.000312665,0.0001817056,0.00018878,0.0001483101,0.00002210979,0.00000491527,0.00006364629],"genre_scores_gemma":[0.9983686,0.0001198387,0.001161878,0.00003698574,0.0002707772,0.000004696869,0.000001943414,0.00002490287,0.00001034576],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01514872,"threshold_uncertainty_score":0.814644,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0107673809648173,"score_gpt":0.2519158000427404,"score_spread":0.2411484190779231,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}