{"id":"W2134071192","doi":"10.1139/v09-070","title":"Studies on chemo- and diastereo-selectivity of the Diels–Alder reactions of sulfinyltoluquinones with cyclopentadiene","year":2009,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Bioactive Compounds and Antitumor Agents","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Cyclopentadiene; Chemistry; Cycloaddition; Adduct; Selectivity; Catalysis; Diels–Alder reaction; Double bond; Organic chemistry; Medicinal chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002008645,0.0001076426,0.0002434632,0.00003858179,0.000126514,0.00000613522,0.0001539005,0.00007809889,0.00006611543],"category_scores_gemma":[0.00008451581,0.00007197883,0.00006447764,0.0001230079,0.0003563,0.00005531204,0.00001036957,0.0003633503,2.320182e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006146017,"about_ca_system_score_gemma":0.000281392,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006406585,"about_ca_topic_score_gemma":0.0004868664,"domain_scores_codex":[0.9993631,0.00004996528,0.0002531159,0.0000896232,0.00008464069,0.0001595081],"domain_scores_gemma":[0.9990527,0.00009379193,0.0003547814,0.00009771865,0.0001993263,0.0002016521],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005707564,0.000409614,0.1979738,0.0002981283,0.0009875294,0.0001352084,0.002401024,0.0001785413,0.7871788,0.0001685892,0.003316375,0.006381636],"study_design_scores_gemma":[0.0008555323,0.0002153928,0.07182723,0.00019184,0.0001219979,0.0003134828,0.0006612993,0.000006889084,0.9214877,0.0001657381,0.004043183,0.0001096875],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9952421,0.0008547374,0.000001957239,0.00106361,0.0001939862,0.00005296894,0.00002268311,0.000001439006,0.002566524],"genre_scores_gemma":[0.9991875,0.0001116853,0.00001951651,0.0002289514,0.00007896915,6.696723e-7,5.010358e-7,0.00000501433,0.000367141],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1343089,"threshold_uncertainty_score":0.2935212,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08995445314155866,"score_gpt":0.3766420962303514,"score_spread":0.2866876430887928,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}