{"id":"W2134071192","doi":"10.1139/v09-070","title":"Studies on chemo- and diastereo-selectivity of the Diels–Alder reactions of sulfinyltoluquinones with cyclopentadiene","year":2009,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Bioactive Compounds and Antitumor Agents","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Cyclopentadiene; Chemistry; Cycloaddition; Adduct; Selectivity; Catalysis; Diels–Alder reaction; Double bond; Organic chemistry; Medicinal chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006129734,0.0005077699,0.0002094537,0.0001423813,0.0002153579,0.0002010881,0.000172516,0.0002318196,0.001679529],"category_scores_gemma":[0.0004654182,0.0002308269,0.0002102102,0.0001773859,0.0003549955,0.0002995566,0.000147675,0.0003982579,0.0003558183],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002583402,"about_ca_system_score_gemma":0.0002504426,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007346891,"about_ca_topic_score_gemma":0.001177582,"domain_scores_codex":[0.9997241,0.00008238921,0.00001370004,0.00004851224,0.0000630853,0.00006818376],"domain_scores_gemma":[0.9996086,0.0001472189,0.00007913083,0.00003325889,0.00008078017,0.00005107945],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000140094,0.00002311985,0.0002063845,0.00004065434,0.000008303879,0.00006110824,0.0001249183,0.0001353796,0.9979346,0.0001627998,0.00003406754,0.001128561],"study_design_scores_gemma":[0.000007322574,0.0001879252,0.0006317763,0.000001508708,0.00000664728,0.00006144415,0.00001237147,0.0001622526,0.998384,0.00002066616,0.0005188659,0.000005173714],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9951553,0.0005786924,0.002062617,0.0000526834,0.00001173906,0.00003110358,0.00009455082,0.00003715812,0.001976098],"genre_scores_gemma":[0.9974245,0.0004489867,0.0009231087,0.00001538823,0.000007027879,0.00001210632,0.00009790525,0.00001266054,0.001058349],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001679529,"threshold_uncertainty_score":0.005618632,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08995445314155866,"score_gpt":0.3766420962303514,"score_spread":0.2866876430887928,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}