{"id":"W2134286493","doi":"10.1002/jssc.200700495","title":"Standard‐free kinetic calibration for rapid on‐site analysis by solid‐phase microextraction","year":2008,"lang":"en","type":"article","venue":"Journal of Separation Science","topic":"Analytical chemistry methods development","field":"Chemistry","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Solid-phase microextraction; Calibration; Chemistry; Chromatography; Analytical Chemistry (journal); BTEX; Standard addition; Acenaphthene; Fluorene; Pyrene; Detection limit; Xylene; Mass spectrometry; Gas chromatography–mass spectrometry; Benzene","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.003471351,0.001699263,0.001088229,0.001178189,0.0006144005,0.0008370657,0.002169774,0.001820713,0.001257529],"category_scores_gemma":[0.003600186,0.0009796699,0.0008482679,0.0009185991,0.0008781349,0.00176085,0.00127946,0.002082279,0.001556751],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008388713,"about_ca_system_score_gemma":0.001570902,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001057192,"about_ca_topic_score_gemma":0.002411106,"domain_scores_codex":[0.9914919,0.001328294,0.0002904296,0.001374302,0.005290886,0.0002242674],"domain_scores_gemma":[0.9979631,0.0004749534,0.0002558557,0.0003706538,0.0008844422,0.00005103827],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001893424,0.0001941284,0.002036223,0.0005551811,0.00009030219,0.00007627128,0.0000913683,0.00205209,0.9144302,0.001753346,0.001155652,0.07737586],"study_design_scores_gemma":[0.00003742708,0.0002684846,0.001688462,0.00003459806,0.00007290747,0.0003840582,0.00004675072,0.02631641,0.9541514,0.0007428967,0.01616083,0.00009572427],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.07592759,0.006057551,0.9099452,0.0003706308,0.0006789144,0.0005737225,0.0003733125,0.00219992,0.003873268],"genre_scores_gemma":[0.4386494,0.006799042,0.5417331,0.0009549062,0.000184577,0.001143435,0.001419854,0.0004933954,0.008622236],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.003471351,"threshold_uncertainty_score":0.01835847,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04269448121110463,"score_gpt":0.4042033819469684,"score_spread":0.3615089007358638,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}