{"id":"W2134547919","doi":"10.1021/jo502074s","title":"Metal–Ligand Binding Interactions in Rhodium/Palladium-Catalyzed Synthesis of Dihydroquinolines","year":2014,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"University of Toronto; Canada Council for the Arts; Alphora Research; Natural Sciences and Engineering Research Council of Canada; Merck","keywords":"Palladium; Rhodium; Catalysis; Chemistry; Ligand (biochemistry); Metal; Combinatorial chemistry; Organic chemistry; Biochemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007635691,0.0002152963,0.0004973916,0.00008755505,0.00009993361,0.00003734577,0.000634012,0.0001048875,0.001203945],"category_scores_gemma":[0.001768611,0.0001676269,0.0002199108,0.0003318902,0.0001774317,0.0001591283,0.0001180075,0.0006394039,0.00001901326],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002215493,"about_ca_system_score_gemma":0.000164723,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004447566,"about_ca_topic_score_gemma":0.00003568201,"domain_scores_codex":[0.998334,0.000005067188,0.0009203288,0.00015477,0.0003342886,0.0002515411],"domain_scores_gemma":[0.9970846,0.00114531,0.0009234536,0.0005630171,0.0001801523,0.00010342],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007929113,0.000142428,0.0007979754,0.0001610253,0.0001467177,0.00000513329,0.0003645237,0.00007454916,0.9978395,0.000001831123,0.00005843926,0.0003285717],"study_design_scores_gemma":[0.0005579406,0.000004776396,0.0002148068,0.0003303816,0.0002887272,0.0008264332,0.0008980155,0.0002224135,0.9961635,0.00007310073,0.0002644137,0.0001554203],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.998061,0.0001544645,0.00006780324,0.000336738,0.0001542741,0.00002757237,0.00001605154,0.0000212031,0.001160912],"genre_scores_gemma":[0.9988409,0.0001056044,0.00004126449,0.000006440695,0.0003736663,0.000002102491,0.000006012112,0.00004035008,0.0005836347],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001675944,"threshold_uncertainty_score":0.9997091,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01360502791012031,"score_gpt":0.2611228885570006,"score_spread":0.2475178606468803,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}